Stereoselective synthesis of spirophosphoranes with a phosphorus—carbon bond based on 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole

被引：0

作者：

L. M. Abdrakhmanova

V. F. Mironov

T. A. Baronova

D. B. Krivolapov

I. A. Litvinov

M. N. Dimukhametov

R. Z. Musin

A. I. Konovalov

机构：

[1] Kazan Research Center of the Russian Academy of Sciences,A. E. Arbuzov Institute of Organic and Physical Chemistry

来源：

Russian Chemical Bulletin | 2008年 / 57卷

关键词：

benzo-1,3,2-dioxaphospholes; hexafluoroacetone; chloral; phosphoranes; spiro compounds; organophosphorus compounds; organofluorine compounds; X-ray diffraction study;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The reactions of 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole containing the carbonyl group in the δ position with respect to the phosphorus atom with chloral and hexafluoroacetone afford tricyclic spirophosphoranes containing a phosphorus—carbon bond with high regio and stereoselectivity. The structures of the spirophosphoranes were established by X-ray diffraction.

引用

页码：1559 / 1563

页数：4

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