Stereoselective synthesis of spirophosphoranes with a phosphorus—carbon bond based on 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole

被引：0
|
作者：
L. M. Abdrakhmanova
V. F. Mironov
T. A. Baronova
D. B. Krivolapov
I. A. Litvinov
M. N. Dimukhametov
R. Z. Musin
A. I. Konovalov
机构：
[1] Kazan Research Center of the Russian Academy of Sciences,A. E. Arbuzov Institute of Organic and Physical Chemistry
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
benzo-1,3,2-dioxaphospholes; hexafluoroacetone; chloral; phosphoranes; spiro compounds; organophosphorus compounds; organofluorine compounds; X-ray diffraction study;
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中图分类号：
学科分类号：
摘要：
The reactions of 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole containing the carbonyl group in the δ position with respect to the phosphorus atom with chloral and hexafluoroacetone afford tricyclic spirophosphoranes containing a phosphorus—carbon bond with high regio and stereoselectivity. The structures of the spirophosphoranes were established by X-ray diffraction.
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页码：1559 / 1563
页数：4
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