Stereoselective synthesis of spirophosphoranes with a phosphorus—carbon bond based on 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole

被引：0
|
作者：
L. M. Abdrakhmanova
V. F. Mironov
T. A. Baronova
D. B. Krivolapov
I. A. Litvinov
M. N. Dimukhametov
R. Z. Musin
A. I. Konovalov
机构：
[1] Kazan Research Center of the Russian Academy of Sciences,A. E. Arbuzov Institute of Organic and Physical Chemistry
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
benzo-1,3,2-dioxaphospholes; hexafluoroacetone; chloral; phosphoranes; spiro compounds; organophosphorus compounds; organofluorine compounds; X-ray diffraction study;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reactions of 2-(2-acetylphenoxy)benzo-1,3,2-dioxaphosphole containing the carbonyl group in the δ position with respect to the phosphorus atom with chloral and hexafluoroacetone afford tricyclic spirophosphoranes containing a phosphorus—carbon bond with high regio and stereoselectivity. The structures of the spirophosphoranes were established by X-ray diffraction.
引用
收藏
页码：1559 / 1563
页数：4
相关论文
共 50 条
  • [31] Synthesis and comparative analysis of the steric and supramolecular structures of diastereomers of 4,4-bis(trifluoromethyl)-2-(fluoroalkoxy)-6,7-benzo-1,3,2λ5- dioxaphosphepin-5-one 2-oxides
    Gubaidullin, AT
    Mironov, VF
    Burnaeva, LM
    Litvinov, IA
    Dobrynin, AB
    Goryunov, EI
    Ivkova, GA
    Konovalova, IV
    Mastryukova, TA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2004, 74 (06) : 842 - 859
  • [32] Synthesis and Comparative Analysis of the Steric and Supramolecular Structures of Diastereomers of 4,4-Bis(trifluoromethyl)-2-(fluoroalkoxy)-6,7-benzo-1,3,2λ5- dioxaphosphepin-5-one 2-Oxides
    A. T. Gubaidullin
    V. F. Mironov
    L. M. Burnaeva
    I. A. Litvinov
    A. B. Dobrynin
    E. I. Goryunov
    G. A. Ivkova
    I. V. Konovalova
    T. A. Mastryukova
    Russian Journal of General Chemistry, 2004, 74 : 842 - 859
  • [33] The interaction of 2-(5-methyl-2-phenyl-2h-1,2,3-diazaphosphol-4-yl)-4h-benzo[e]-1,3,2-dioxaphosphinin-4-one with activated carbonyl compounds. Synthesis of bis-heterocyclic systems containing di- and tetracoordinated phosphorus
    Mironov, Vladimir F.
    Ivkova, Gulnara A.
    Abdrakhmanova, Liliya M.
    Musin, Rashid Z.
    Mironova, Ekaterina V.
    Krivolapov, Dmitry B.
    Gubaidullin, Aidar T.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2018, 193 (01) : 53 - 62
  • [34] P-Cl bond-induced lactamization of 2(2′-hydroxyl)-phenyloxazoline to form a cyclic phosphinite, 3-(2-chloroethyl)-2-phenyl-2H-benzo[e][1,3,2]oxazaphosphinin-4(3H)-one: synthesis, structural studies and transition metal complexes
    Chaubey, Bimba
    Mobin, Shaikh M.
    Balakrishna, Maravanji S.
    DALTON TRANSACTIONS, 2014, 43 (02) : 584 - 591
  • [35] Phosphorus-carbon bond cleavage of Ph2PCH2PPh2 at a triruthenium center:: synthesis and structural characterization of [Ru3(μ-CO)(CO)6(μ-PPh2)2(μ3-CH2PPh)]
    Kabir, SE
    Karim, M
    Malik, KMA
    Siddiquee, TA
    INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (04) : 128 - 130
  • [36] Synthesis, structure and properties of cholesterol-based A(LS)2- and A(LS)3-type gelators without hydrogen bond linkers
    Shimasaki, Toshiaki
    Okamiya, Yuta
    Sato, Ryota
    Hara, Kazuyoshi
    Nakamura, Taro
    Teramoto, Naozumi
    Shibata, Mitsuhiro
    TETRAHEDRON, 2016, 72 (12) : 1517 - 1523
  • [37] Synthesis and characterization of 2-substituted 5,6-benzo-1-methyl-3-R-1,3,2-diazaphosphorin-4-ones (R=2-morpholinoethyl, 1-adamantyl) containing phosphorus with coordination numbers three, four and five
    Borkenhagen, F
    Neda, I
    Thonnessen, H
    Jones, PG
    Schmutzler, R
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (11): : 1627 - 1638
  • [38] A new asymmetric carbon-carbon bond forming reaction: Four-component stereoselective synthesis of (Z)-4,6-dihydroxy-3-methylalk-2-enyl methyl sulfones
    Narkevitch, V
    Schenk, K
    Vogel, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (10) : 1806 - +
  • [39] A new asymmetric carbon-carbon bond forming reaction: Four-component stereoselective synthesis of (Z)-4,6-dihydroxy-3-methylalk-2-enyl methyl sulfones
    Narkevitch, Vera
    Schenk, Kurt
    Vogel, Pierre
    Angewandte Chemie (International Edition in English), 2000, 39 (10): : 1806 - 1808
  • [40] Synthesis and Antitumor Molecular Mechanism of Agents Based on Amino 2-(3′,4′,5′-Trimethoxybenzoyl)benzo[b]furan: Inhibition of Tubulin and Induction of Apoptosis
    Romagnoli, Romeo
    Baraldi, Pier Giovanni
    Lopez-Cara, Carlota
    Cruz-Lopez, Olga
    Carrion, Maria Dora
    Salvador, Maria Kimatrai
    Bermejo, Jaime
    Estevez, Sara
    Estevez, Francisco
    Balzarini, Jan
    Brancale, Andrea
    Ricci, Antonio
    Chen, Longchuan
    Kim, Jae Gwan
    Hamel, Ernest
    CHEMMEDCHEM, 2011, 6 (10) : 1841 - 1853
12345