New Ni(II) and Co(II) coordination polymers: synthesis, structures and magnetic properties

被引：0

作者：

Jing Li

Jiangtao Li

Huiqing Shi

Di Qu

机构：

[1] Xi’an University,Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, School of Chemical Engineering

[2] General Hospital of Western Theater Command,Department of Clinical Pharmacy

来源：

Journal of the Iranian Chemical Society | 2022年 / 19卷

关键词：

Coordination polymer; Co-complex; Magnetic properties;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Using 4-(3-Carboxyphenyl)picolinic acid (H2cppa), a pyridine-carboxylate ligand to react with its relevant metal salts in the existence of a second N-donor chelating ligand 2,2'-bipyridine (2,2'-bipy) under different reaction conditions, two new coordination polymers (CPs) were produced, and their chemical formulae are {[Ni(μ-cppa)(2,2′-bipy)(H2O)]·H2O}n (1) and [Co(μ-cppa)(2,2′-bipy)(H2O)]n (2). The magnetic investigations indicate that the two compounds prepared possess the antiferromagnetic coupling between neighboring metallic ions.

引用

页码：3861 / 3868

页数：7

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