New Ni(II) and Co(II) coordination polymers: synthesis, structures and magnetic properties

被引：0
|
作者：
Li, Jing [1 ]
Li, Jiangtao [1 ]
Shi, Huiqing [2 ]
Qu, Di [2 ]
机构：
[1] Xian Univ, Sch Chem Engn, Key Lab Surface Engn & Remfg Shaanxi Prov, Xian, Shaanxi, Peoples R China
[2] Gen Hosp Western Theater Command, Dept Clin Pharm, Chengdu, Sichuan, Peoples R China
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2022年 / 19卷 / 09期
关键词：
Coordination polymer; Co-complex; Magnetic properties; FLUORESCENT; CHAINS; SERIES;
D O I：
10.1007/s13738-022-02565-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Using 4-(3-Carboxyphenyl)picolinic acid (H(2)cppa), a pyridine-carboxylate ligand to react with its relevant metal salts in the existence of a second N-donor chelating ligand 2,2'-bipyridine (2,2'-bipy) under different reaction conditions, two new coordination polymers (CPs) were produced, and their chemical formulae are {[Ni(mu-cppa)(2,2 '-bipy)(H2O)]center dot H2O}(n) (1) and [Co(mu-cppa)(2,2 '-bipy)(H2O)](n) (2). The magnetic investigations indicate that the two compounds prepared possess the antiferromagnetic coupling between neighboring metallic ions.
引用
收藏
页码：3861 / 3868
页数：8
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