Crystal structure of a new modification of the cyanide-bridged copper(I) coordination compound [CuCN(bpy)]n

被引：0
|
作者：
A. V. Ermolaev
A. I. Smolentsev
Yu. V. Mironov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[2] Siberian Branch,undefined
[3] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2014年 / 55卷
关键词：
cyanide complex; copper (I); hydrothermal synthesis; crystal structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The hydrothermal reaction of CuCN and bpy in the presence of an octahedral cluster complex K2.75Cs1.25[Re6Se8(CN)4(OH)2]·H2O affords a cyanide-bridged chain coordination polymer [CuCN(bpy)]n (bpy — 2,2′-bipyridyl) (1). The structure is monoclinic, space group C2/c, a = 22.848(2) Å, b = 7.7182(8) Å, c = 14.4331(13) Å, β = 127.805(2)°, V = 2010.9(3) Å3, Z = 8, dx = 1.623 g/cm3. Copper atoms have a tetrahedral coordination environment formed by N atoms of the bpy molecule as well as N and C atoms of ambidentate bridging CN ligands.
引用
收藏
页码：731 / 733
页数：2
相关论文
共 50 条
  • [1] Crystal structure of a new modification of the cyanide-bridged copper(I) coordination compound [CuCN(bpy)] n
    Ermolaev, A. V.
    Smolentsev, A. I.
    Mironov, Yu. V.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (04) : 731 - 733
  • [2] Synthesis, crystal structure and magnetic properties of a new cyanide-bridged mixed-valence copper(I)/copper(II) clathrate
    Visinescu, Diana
    Fabelo, Oscar
    Ruiz-Perez, Catalina
    Lloret, Francesc
    Julve, Miguel
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 : 252 - 254
  • [3] Synthesis and crystal structures of four cyanide-bridged coordination polymers
    He, X
    Lu, CZ
    Yuan, DQ
    Chen, SM
    Chen, JT
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (11) : 2181 - 2188
  • [4] CRYSTAL STRUCTURE OF COPPER(I) CYANIDE HYDRAZINE COMPLEX CUCN.N2H4
    CROMER, DT
    LARSON, AC
    ROOF, RB
    [J]. ACTA CRYSTALLOGRAPHICA, 1966, 20 : 279 - &
  • [5] Hydrothermal.synthesis and crystal structure of a novel cyanide-bridged double helical copper(I) coordination polymer [Cu3(CN)3(phen)]n
    Liang, Sheng-Wen
    Li, Ming-Xing
    Shao, Min
    Miao, Zhi-Xin
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (12) : 1312 - 1314
  • [6] Novel 1-D copper cyanide-bridged coordination polymers.
    Yan, BB
    Lachgar, A
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U890 - U891
  • [7] Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain
    Alexandru, Maria-Gabriela
    Visinescu, Diana
    Shova, Sergiu
    Lloret, Francesc
    Julve, Miguel
    [J]. DALTON TRANSACTIONS, 2017, 46 (01) : 39 - 43
  • [8] Synthesis,Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex
    孙志豪
    王勇
    马骁
    王艳龙
    胡胜民
    盛天录
    吴新涛
    [J]. Chinese Journal of Structural Chemistry, 2014, 33 (09) : 1305 - 1310
  • [9] Synthesis, Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex
    Sun Zhi-Hao
    Wang Yong
    Ma Xiao
    Wang Yan-Long
    Hu Sheng-Min
    Sheng Tian-Lu
    Wu Xin-Tao
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (09) : 1305 - 1310
  • [10] Synthesis, crystal structure and magnetic properties of a new 2D cyanide-bridged heterobimetallic Cr(I)-Mn(III) complex
    Zhang, Daopeng
    Zhang, Li-Fang
    Wang, Hailong
    Chen, Yuting
    Ni, Zhong-Hai
    Jiang, Jianzhuang
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (07) : 895 - 898
12345