Synthesis,Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex

被引：0
|
作者：
孙志豪 [1 ,2 ]
王勇 [1 ,2 ]
马骁 [2 ]
王艳龙 [1 ,2 ]
胡胜民 [1 ]
盛天录 [1 ]
吴新涛 [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
[2] Graduate School of the Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2014年 / 33卷 / 09期
基金：
中国国家自然科学基金;
关键词：
cyanide-bridged; mixed-valence; binuclear; MMCT; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2014.09.029
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A new mixed-valence cyanide-bridged complex, Br3Fe(μ-NC)RuBr(dppm)2(dppm = bis(diphenylphosphino)methane), was obtained through the reaction between trans-(dppm)2ClRuCN and FeBr3. Its crystal structure was characterized. Electronic absorption spectra indicate the existence of metal-to-metal charge transfer(MMCT) and this complex is Class Ⅱ mixed valence complexes according to the classification of Robin and Day. Magnetic analysis shows it is paramagnetic.
引用
收藏
页码：1305 / 1310
页数：6
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