Cyanide-Bridged Heterobimetallic Fe(III)-Mn(II) Complex: Synthesis, Crystal Structure and Magnetic Property

被引：0

作者：

Chen, Xia ^{[1
]}

Zhao, Zengdian ^{[1
]}

Wang, Ping ^{[1
]}

Zhang, Daopeng ^{[1
]}

机构：

[1] Shandong Univ Technol, Coll Chem Engn, Zibo 255049, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 13期

关键词：

Cyanide-bridged; Crystal structure; Magnetic property; BUILDING-BLOCK;

D O I：

10.14233/ajchem.2014.16307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cyanide-bridged heterobimetallic trinuclear Fe(III)-Mn(II) complex with the formula {[Fe(pcq)(CN)(3)](2)[Mn(CH3OH)(4)]}(1) has been synthesized with mer-[PPh4][Fe(pcq)(CN)(3)] (pcq = 8-(pyridine-2-carboxamido)quinoline anion) as building block and [Mn(ClO4)](2)center dot 6H(2)O as assemble segment. Single X-ray diffraction reveals its neutral trinuclear Fe2Mn nature, in which the two cyanide-containing building blocks acting as a monodentate ligand are coordinated to the central Mn(II) ion. Investigation over its magnetic property shows the antiferromagnetic magnetic coupling between the cyanide-bridged neighboring Fe(III) and Mn(II) ions.

引用

页码：3986 / 3988

页数：3

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