Hydrothermal.synthesis and crystal structure of a novel cyanide-bridged double helical copper(I) coordination polymer [Cu3(CN)3(phen)]n

被引：36
|
作者：
Liang, Sheng-Wen
Li, Ming-Xing [1 ]
Shao, Min
Miao, Zhi-Xin
机构：
[1] Shanghai Univ, Dept Chem, Coll Sci, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Instrumental Anal & Res Ctr, Shanghai 200444, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 12期
关键词：
copper(I) cyanide; coordination polymer; hydrothermal synthesis; double helix; crystal structure; fluorescence;
D O I：
10.1016/j.inoche.2006.08.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reaction of CuCN, K-3[Fe(CN)(6)] and 1,10-phenanthroline affords a novel cyanide-bridged copper(I) coordination polymer [Cu-3(CN)(3)(phen)](n) (1). The complex displays an interesting one-dimensional neutral double helical framework with (phen)Cu-CN-side-arms as interchain bridges. The double helical chains are close packed in a parallel fashion, and the phen ligands stack in an interpenetrating mode, which leads to pi-pi interactions between parallel phen planes. The thermal stability and fluorescent property have also been investigated. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：1312 / 1314
页数：3
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