Crystal structure of a new modification of the cyanide-bridged copper(I) coordination compound [CuCN(bpy)]n

被引：0
|
作者：
A. V. Ermolaev
A. I. Smolentsev
Yu. V. Mironov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[2] Siberian Branch,undefined
[3] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2014年 / 55卷
关键词：
cyanide complex; copper (I); hydrothermal synthesis; crystal structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The hydrothermal reaction of CuCN and bpy in the presence of an octahedral cluster complex K2.75Cs1.25[Re6Se8(CN)4(OH)2]·H2O affords a cyanide-bridged chain coordination polymer [CuCN(bpy)]n (bpy — 2,2′-bipyridyl) (1). The structure is monoclinic, space group C2/c, a = 22.848(2) Å, b = 7.7182(8) Å, c = 14.4331(13) Å, β = 127.805(2)°, V = 2010.9(3) Å3, Z = 8, dx = 1.623 g/cm3. Copper atoms have a tetrahedral coordination environment formed by N atoms of the bpy molecule as well as N and C atoms of ambidentate bridging CN ligands.
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页码：731 / 733
页数：2
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