Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)

被引:0
|
作者
Yu. A. Vorotnikov
M. A. Mikhailov
K. A. Brylev
D. A. Piryazev
N. V. Kuratieva
M. N. Sokolov
Yu. V. Mironov
M. A. Shestopalov
机构
[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
[3] Scientific Institute of Clinical and Experimental Lymphology,undefined
来源
Russian Chemical Bulletin | 2015年 / 64卷
关键词
molybdenum; tungsten; octahedral cluster complexes; crystal structure; luminescence;
D O I
暂无
中图分类号
学科分类号
摘要
Two new compounds based on octahedral molybdenum and tungsten iodide cluster complexes of the composition (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) were synthesized and structurally characterized. The luminescence properties of powder samples of the synthesized compounds and of the salts (Bu4N)2[{M6(µ3-I)8}I6] described earlier were investigated. Due to the presence of the vinylcontaining cation, these compounds can be involved in radical copolymerization in order to produce polymeric luminescent materials.
引用
收藏
页码:2591 / 2596
页数:5
相关论文
共 50 条
  • [1] Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(μ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)
    Vorotnikov, Yu. A.
    Mikhailov, M. A.
    Brylev, K. A.
    Piryazev, D. A.
    Kuratieva, N. V.
    Sokolov, M. N.
    Mironov, Yu. V.
    Shestopalov, M. A.
    RUSSIAN CHEMICAL BULLETIN, 2015, 64 (11) : 2591 - 2596
  • [2] Tosylate Cluster Complexes (Bu4N)2[M6I8(O3SC6H4CH3)6] (M = Mo, W)
    Mikhailov, M. A.
    Gushchin, A. L.
    Gallyamov, M. R.
    Virovets, A. V.
    Sokolov, M. N.
    Sheven, D. G.
    Pervukhin, V. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (03) : 172 - 180
  • [3] Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)
    M. A. Mikhailov
    A. L. Gushchin
    M. R. Gallyamov
    A. V. Virovets
    M. N. Sokolov
    D. G. Sheven’
    V. V. Pervukhin
    Russian Journal of Coordination Chemistry, 2017, 43 : 172 - 180
  • [4] Synthesis of an unprecedented bicapped adamantold [CU6(μ2-I)(μ3-I)4(μ4-I)(m-tolyl3P)4(CH3CN)2] cluster
    Lobana, TS
    Kaur, P
    Nishioka, T
    INORGANIC CHEMISTRY, 2004, 43 (13) : 3766 - 3767
  • [5] Crystal structures and luminescence properties of Li6MN4:Ce3+ (M = Mo, W)
    Klotz, Martin
    Seibald, Markus
    Baumann, Dominik
    Wurst, Klaus
    Heymann, Gunter
    Huppertz, Hubert
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2023, 78 (11-12): : 557 - 565
  • [6] Synthesis, Crystal Structure, and Luminescence of Metal Iodide Cluster Compounds (nBu4N)2[M6I8(NCO)6] withM= Mo, W
    Fuhrmann, Arin-Daniel
    Pachel, Florian
    Stroebele, Markus
    Enseling, David
    Juestel, Thomas
    Meyer, Hans-Juergen
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (19): : 1650 - 1654
  • [7] Synthesis and crystal structure of VS4Cu6Py8I3
    Chen, DG
    Zhang, HH
    Yu, XF
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (05) : 591 - 594
  • [8] Phosphorescent complexes of {Mo6I8}4+ with triazolates: [2+3] cycloaddition of alkynes to [Mo6I8(N3)6]2-
    Mironova, Alina D.
    Mikhailov, Maksim A.
    Brylev, Konstantin A.
    Gushchin, Artem L.
    Sukhikh, Taisiya S.
    Sokolov, Maxim N.
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (47) : 20620 - 20625
  • [9] SYNTHESIS OF 2 NOVEL HETEROBIMETALLIC CLUSTER COMPOUNDS [NET4]4[MS4CU4I6] (M=MO,W) - CRYSTAL-STRUCTURE OF [NET4]4[MOS4CU4I6]
    LANG, JP
    ZHOU, WY
    XIN, XQ
    KU, KB
    JOURNAL OF COORDINATION CHEMISTRY, 1993, 30 (02) : 173 - 182
  • [10] [Mo6I8]4+ complexes with tetrazolate ligands: [3+2] cycloaddition of aromatic nitriles to [Mo6I8(N3)6]2-
    Mironova, Alina
    Gushchin, Artem
    Abramov, Pavel
    Eltsov, Ilia
    Ryadun, Alexey
    Sokolov, Maxim
    POLYHEDRON, 2021, 205