Tosylate Cluster Complexes (Bu4N)2[M6I8(O3SC6H4CH3)6] (M = Mo, W)

被引：13
|
作者：
Mikhailov, M. A. [1 ]
Gushchin, A. L. [1 ,2 ]
Gallyamov, M. R. [1 ]
Virovets, A. V. [1 ,2 ]
Sokolov, M. N. [1 ,2 ]
Sheven, D. G. [1 ]
Pervukhin, V. V. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 43卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
clusters; molybdenum; tungsten; iodides; p-toluenesulfonates; crystal structure; solvolysis; CRYSTAL-STRUCTURES; SUBSTITUTION CHEMISTRY; HEXANUCLEAR MOLYBDENUM; I CLUSTERS; BR; LUMINESCENCE; PRECURSOR; CORE; CL; HALIDES;
D O I：
10.1134/S107032841702004X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of (Bu4N)(2)[M6I14] with silver p-toluenesulfonate (tosylate) AgO3SC6H4CH3 affords iodide cluster complexes (Bu4N)(2)[M6I8(pts)(6)] (M = Mo (I), W (II); pts is tosylate anion CH3C6H4SO3). According to the X-ray diffraction data (CIF file CCDC no. 1027969), the molybdenum atoms in (Bu4N)(2)[Mo6I8(pts)(6)] center dot 2Et(2)O center dot 2MeCN (I') are coordinated via the monodentate mode by the tosylate ligands. The H-1 NMR and mass spectrometry data show that in donor solvents the complexes undergo solvolysis followed by the substitution of the tosylate ligands by the solvent molecules, which is accompanied by changes in the electrochemical properties, as shown by the cyclic voltammetry data.
引用
收藏
页码：172 / 180
页数：9
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