Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)

被引：0

作者：

Yu. A. Vorotnikov

M. A. Mikhailov

K. A. Brylev

D. A. Piryazev

N. V. Kuratieva

M. N. Sokolov

Yu. V. Mironov

M. A. Shestopalov

机构：

[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry

[2] Novosibirsk State University,undefined

[3] Scientific Institute of Clinical and Experimental Lymphology,undefined

来源：

Russian Chemical Bulletin | 2015年 / 64卷

关键词：

molybdenum; tungsten; octahedral cluster complexes; crystal structure; luminescence;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two new compounds based on octahedral molybdenum and tungsten iodide cluster complexes of the composition (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) were synthesized and structurally characterized. The luminescence properties of powder samples of the synthesized compounds and of the salts (Bu4N)2[{M6(µ3-I)8}I6] described earlier were investigated. Due to the presence of the vinylcontaining cation, these compounds can be involved in radical copolymerization in order to produce polymeric luminescent materials.

引用

页码：2591 / 2596

页数：5

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