Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)

被引：0
|
作者：
Yu. A. Vorotnikov
M. A. Mikhailov
K. A. Brylev
D. A. Piryazev
N. V. Kuratieva
M. N. Sokolov
Yu. V. Mironov
M. A. Shestopalov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
[3] Scientific Institute of Clinical and Experimental Lymphology,undefined
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
molybdenum; tungsten; octahedral cluster complexes; crystal structure; luminescence;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two new compounds based on octahedral molybdenum and tungsten iodide cluster complexes of the composition (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) were synthesized and structurally characterized. The luminescence properties of powder samples of the synthesized compounds and of the salts (Bu4N)2[{M6(µ3-I)8}I6] described earlier were investigated. Due to the presence of the vinylcontaining cation, these compounds can be involved in radical copolymerization in order to produce polymeric luminescent materials.
引用
收藏
页码：2591 / 2596
页数：5
相关论文
共 50 条
  • [31] Synthesis, structure, and properties of molybdenum and tungsten cyano complexes with cuboidal M4(μ3-E)4 (M = Mo, W; E = S, Se, Te) cores
    Fedin, VP
    Kalinina, IV
    Samsonenko, DG
    Mironov, YV
    Sokolov, MN
    Tkachev, SV
    Virovets, AV
    Podberezskaya, NV
    Elsegood, MRJ
    Clegg, W
    Sykes, AG
    INORGANIC CHEMISTRY, 1999, 38 (09) : 1956 - 1965
  • [32] SYNTHESIS AND CRYSTAL-STRUCTURE OF ALKALI-METAL OXO NITRIDO DIMETALLATES(VI), A(6)[M(2)N(4)O(3)] (A=K, RB, CS, M=MO, W)
    NIEWA, R
    JACOBS, H
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 217 (01) : 38 - 43
  • [33] Synthesis and crystal structure of alkali metal oxo nitrido dimetallates(VI), A6[M2N4O3] (A ≡ K, Rb, Cs; M ≡ Mo, W)
    Niewa, R.
    Jacobs, H.
    1600, Elsevier Science S.A., Lausanne, Switzerland (217):
  • [34] Synthesis, structure, and luminescence of the octahedral molybdenum cluster [Mo6I8(SC6F4H)6]2-
    Sokolov, M. N.
    Mikhailov, M. A.
    Virovets, A. V.
    Brylev, K. A.
    Bredikhin, R. A.
    Maksimov, A. M.
    Platonov, V. E.
    Fedin, V. P.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (08) : 1764 - 1767
  • [35] Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)
    Han, Shujuan
    Bai, Chunyan
    Zhang, Bingbing
    Yang, Zhihua
    Pan, Shilie
    JOURNAL OF SOLID STATE CHEMISTRY, 2016, 237 : 14 - 18
  • [36] Trimethylphosphine halide complexes of titanium, zirconium and hafnium in oxidation states IV, III and II. Crystal structure of MI4(PMe3)n (M=Zr, n=3; M=Hf, n=2.5), M2X6(PMe3)4 (M=Hf, Ti, X=I; M=Zr, X=Br) and (ae-@eta6,eta6-@C6H6)Hf2I4(PMe3)4 QQ C6$ /H$-6
    Inorg Chim Acta, 1 (180):
  • [37] Synthesis and crystal structure of tetranuclear copper(I) and silver(I) complexes bridged by 2-amino-1,3,4-thiadiazole (atdz):: [Cu4(atdz)6](ClO4)4 • 2CH3OH and [Ag4(atdz)6](ClO4)4
    Maekawa, M
    Munakata, M
    Kuroda-Sowa, T
    Suenaga, Y
    Sugimoto, K
    INORGANICA CHIMICA ACTA, 1999, 290 (02) : 153 - 158
  • [38] MECHANOCHEMICAL SYNTHESIS OF SOLUBLE COMPLEXES CONTAINING M3S74+ AND M3SE74+ FRAGMENTS FROM POLYMERIC M3Y7BR4 (M = MO, W, Y = S, SE) - THE CRYSTAL-STRUCTURE OF (PPN)2W3S7CL6
    FEDIN, VP
    SOKOLOV, MN
    MYAKISHEV, KG
    GERASKO, OA
    FEDOROV, VY
    MACICEK, J
    POLYHEDRON, 1991, 10 (12) : 1311 - 1317
  • [39] Theory of an Fm3m→I4/m structural phase transition in an Rb2KScF6 crystal
    V. I. Zinenko
    N. G. Zamkova
    Journal of Experimental and Theoretical Physics, 2000, 91 : 314 - 323
  • [40] Theory of an Fm3m → I4/m structural phase transition in an Rb2KScF6 crystal
    Zinenko, VI
    Zamkova, NG
    JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS, 2000, 91 (02) : 314 - 323
12345