Synthesis of Thermally Stable Tetragonal Zirconia with Large Surface Area and Its Catalytic Activity in the Skeletal Isomerization of 1-Butene

被引：0

作者：

Young-Woong Suh

Jung-Woo Lee

Hyun-Ku Rhee

机构：

[1] Seoul National University,School of Chemical Engineering and Institute of Chemical Processes

来源：

Catalysis Letters | 2003年 / 90卷

关键词：

tetragonal zirconia; mesoporous material; microporous contribution; large surface area; thermal stability; skeletal isomerization; 1-butene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Thermally stable zirconia with a large BET surface area was prepared by using zirconium atrane derivatives and commercial alkyltrimethylammonium bromide. The zirconia samples were characterized by wide-angle X-ray diffraction, thermal analysis and N2 adsorption/desorption analysis. The results showed that the present zirconia existed as a thermally stable tetragonal crystallite and consisted of mesoporous material with microporous contribution. The BET surface area was found larger than 240 m2/g even after calcination at 600 °C. The present zirconia after sulfation was applied to the skeletal isomerization of 1-butene, and its catalytic activity was found superior to that of the conventional sulfated zirconia.

引用

页码：103 / 109

页数：6

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