Synthesis of Thermally Stable Tetragonal Zirconia with Large Surface Area and Its Catalytic Activity in the Skeletal Isomerization of 1-Butene

被引：0
|
作者：
Young-Woong Suh
Jung-Woo Lee
Hyun-Ku Rhee
机构：
[1] Seoul National University,School of Chemical Engineering and Institute of Chemical Processes
来源：
Catalysis Letters | 2003年 / 90卷
关键词：
tetragonal zirconia; mesoporous material; microporous contribution; large surface area; thermal stability; skeletal isomerization; 1-butene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Thermally stable zirconia with a large BET surface area was prepared by using zirconium atrane derivatives and commercial alkyltrimethylammonium bromide. The zirconia samples were characterized by wide-angle X-ray diffraction, thermal analysis and N2 adsorption/desorption analysis. The results showed that the present zirconia existed as a thermally stable tetragonal crystallite and consisted of mesoporous material with microporous contribution. The BET surface area was found larger than 240 m2/g even after calcination at 600 °C. The present zirconia after sulfation was applied to the skeletal isomerization of 1-butene, and its catalytic activity was found superior to that of the conventional sulfated zirconia.
引用
收藏
页码：103 / 109
页数：6
相关论文
共 50 条
  • [21] PROPERTIES OF MAGNESIUM OXIDES PREPARED FROM VARIOUS SALTS AND THEIR CATALYTIC ACTIVITY IN 1-BUTENE ISOMERIZATION
    MATSUDA, T
    TANABE, J
    HAYASHI, N
    SASAKI, Y
    MIURA, H
    SUGIYAMA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (04) : 990 - 994
  • [22] Effect of Acid Amount and Acid Sites Distribution of Ferrierite Zeolite on the Catalytic Behavior in the 1-Butene Skeletal Isomerization
    Ge, Junping
    Hu, Yunfeng
    Bao, Qiang
    Zhang, Jian
    Wu, Guoliang
    Sun, Penglai
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2023, 97 (10) : 2125 - 2135
  • [23] Investigations into the origin of the remarkable catalytic performance of aged H-ferrierite for the skeletal isomerization of 1-butene to isobutene
    Lee, SH
    Shin, CH
    Hong, SB
    JOURNAL OF CATALYSIS, 2004, 223 (01) : 200 - 211
  • [24] Effect of Acid Amount and Acid Sites Distribution of Ferrierite Zeolite on the Catalytic Behavior in the 1-Butene Skeletal Isomerization
    Junping Ge
    Yunfeng Hu
    Qiang Bao
    Jian Zhang
    Guoliang Wu
    Penglai Sun
    Russian Journal of Physical Chemistry A, 2023, 97 : 2125 - 2135
  • [25] CATALYTIC ACTIVITY FOR 1-BUTENE ISOMERIZATION AND ELECTRON-DONATING PROPERTY NIO-ZNO CATALYST
    KAGEYAMA, Y
    AOMURA, K
    NIPPON KAGAKU KAISHI, 1974, (10) : 1847 - 1851
  • [26] SYNTHESIS AND CHARACTERIZATION OF ZSM-22 ZEOLITES AND THEIR CATALYTIC BEHAVIOR IN 1-BUTENE ISOMERIZATION-REACTIONS
    SIMON, MW
    SUIB, SL
    OYOUNG, CL
    JOURNAL OF CATALYSIS, 1994, 147 (02) : 484 - 493
  • [27] Comparison of the catalytic properties of Al-ZSM-22 and Fe-ZSM-22 in the skeletal isomerization of 1-butene
    Byggningsbacka, R
    Kumar, N
    Lindfors, LE
    CATALYSIS LETTERS, 1999, 58 (04) : 231 - 234
  • [28] Skeletal isomerization of 1-butene on tungsten oxide catalysts supported on activated carbons with various surface oxygen contents
    Moreno-Castilla, C
    Pérez-Cadenas, AF
    Maldonado-Hódar, FJ
    Carrasco-Marín, F
    CARBON, 2003, 41 (04) : 863 - 866
  • [29] Comparative study of the catalytic properties of ZSM-22 and ZSM-35 ferrierite zeolites in the skeletal isomerization of 1-butene
    Byggningsbacka, R
    Kumar, N
    Lindfors, LE
    JOURNAL OF CATALYSIS, 1998, 178 (02) : 611 - 620
  • [30] SURFACE-PROPERTIES AND CATALYTIC ACTIVITIES OF SUPERCONDUCTING BI-PB-SR-CA-CU OXIDES FOR 1-BUTENE ISOMERIZATION
    TADA, A
    ISHIDA, R
    OKAZAKI, N
    IMIZU, Y
    ITOH, H
    ACID-BASE CATALYSIS II, 1994, 90 : 321 - 326
12345