Pentamethylcyclopentadienylruthenium(II) Complexes: Synthesis, Characterization and Catalytic Activity in Aryl–Aryl Coupling

被引：0
|
作者：
Vettaikaranpudur G. Gnanasoundari
Karuppannan Natarajan
机构：
[1] Bharathiar University,Department of Chemistry
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Physical Chemistry; Inorganic Chemistry; Catalytic Activity; Aniline; Ruthenium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Ruthenium(II) complexes of the type [Ru(PPh3)(η5-C5Me5)L] have been synthesized by the reactions of [RuCl(PPh3)2(η5-C5Me5)] with Schiff bases having the (N, O) donor atoms. The Schiff bases used in this study were prepared by condensing the appropriate aniline with salicylaldehyde or 2-hydroxy-1-naphthaldehyde in a 1:2 molar ratio respectively. The complexes were characterized by analytical, spectral (i.r., electronic and 1H-n.m.r.) data. The new complexes have been used as catalysts in aryl–aryl coupling reactions.
引用
下载
收藏
页码：376 / 379
页数：3
相关论文
共 50 条
  • [1] Pentamethylcyclopentadienylruthenium(II) complexes: Synthesis, characterization and catalytic activity in aryl-aryl coupling
    Gnanasoundari, VG
    Natarajan, K
    TRANSITION METAL CHEMISTRY, 2004, 29 (04) : 376 - 379
  • [2] Ruthenium(III) Schiff base complexes: Catalytic activity in aryl-aryl coupling reaction and antimicrobial activity
    Jayabalakrishnan, C
    Karvembu, R
    Natarajan, K
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (09): : 1535 - 1553
  • [3] Synthesis and Characterization of Aryl Acylguanidines and Their Copper(II) Complexes
    Zhou Qi
    Zhang Zhi-Jiao
    Wang Fan-Fan
    Han Li
    Zhu Cheng-Ben
    Li Hai-Pu
    Yang Ying
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (08) : 1283 - 1296
  • [4] (Phosphinito)aryl benzimidazole PCN pincer palladium(II) complexes: Synthesis, characterization and catalytic activity in C-H arylation of azoles with aryl iodides
    Wang, Cong
    Li, Yang
    Lu, Beibei
    Hao, Xin-Qi
    Gong, Jun-Fang
    Song, Mao-Ping
    POLYHEDRON, 2018, 143 : 184 - 192
  • [5] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl–aryl couplings and biological activity
    Ramasamy Karvembu
    Chinnasamy Jayabalakrishnan
    Nallasamy Dharmaraj
    Somanur V. Renukadevi
    Karuppannan Natarajan
    Transition Metal Chemistry, 2002, 27 : 631 - 638
  • [6] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl-aryl couplings and biological activity
    Karvembu, R
    Jayabalakrishnan, C
    Dharmaraj, N
    Renukadevi, SV
    Natarajan, K
    TRANSITION METAL CHEMISTRY, 2002, 27 (06) : 631 - 638
  • [7] Synthesis, characterization and catalytic activities of Zn(II) and Cd(II) complexes supported by unsymmetrical aryl thiourea ligands
    Banerjee, Indrani
    Bhattacharjee, Jayeeta
    Kumar, Ravi
    Pal, Kuntal
    Panda, Tarun K.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2023, 649 (05):
  • [8] Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
    Huang, Wei
    Lu, Jiahui
    Fan, Qingqing
    Li, Xiaoyan
    Hinz, Alexander
    Sun, Hongjian
    NEW JOURNAL OF CHEMISTRY, 2022, 46 (16) : 7512 - 7521
  • [9] SYNTHESIS AND CHARACTERIZATION OF PALLADIUM(II) COMPLEXES WITH ARYL TELLUROLS AND DIARYL DITELLURIDES
    KHANDELWAL, BL
    KUNDU, K
    GUPTA, SK
    INORGANICA CHIMICA ACTA, 1988, 154 (02) : 183 - 188
  • [10] Nickel(ii) complexes with novel nitron-type NHC ligands: synthesis and catalytic activity in the Suzuki-Miyaura coupling of aryl chlorides
    Pyatachenko, Anastasia S.
    Chernenko, Andrey Yu.
    Soliev, Safarmurod B.
    Minyaev, Mikhail E.
    Chernyshev, Victor M.
    MENDELEEV COMMUNICATIONS, 2024, 34 (01) : 39 - 42
12345