Pentamethylcyclopentadienylruthenium(II) Complexes: Synthesis, Characterization and Catalytic Activity in Aryl–Aryl Coupling

被引:0
|
作者
Vettaikaranpudur G. Gnanasoundari
Karuppannan Natarajan
机构
[1] Bharathiar University,Department of Chemistry
来源
关键词
Physical Chemistry; Inorganic Chemistry; Catalytic Activity; Aniline; Ruthenium;
D O I
暂无
中图分类号
学科分类号
摘要
Ruthenium(II) complexes of the type [Ru(PPh3)(η5-C5Me5)L] have been synthesized by the reactions of [RuCl(PPh3)2(η5-C5Me5)] with Schiff bases having the (N, O) donor atoms. The Schiff bases used in this study were prepared by condensing the appropriate aniline with salicylaldehyde or 2-hydroxy-1-naphthaldehyde in a 1:2 molar ratio respectively. The complexes were characterized by analytical, spectral (i.r., electronic and 1H-n.m.r.) data. The new complexes have been used as catalysts in aryl–aryl coupling reactions.
引用
收藏
页码:376 / 379
页数:3
相关论文
共 50 条
  • [1] Pentamethylcyclopentadienylruthenium(II) complexes: Synthesis, characterization and catalytic activity in aryl-aryl coupling
    Gnanasoundari, VG
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2004, 29 (04) : 376 - 379
  • [2] Ruthenium(III) Schiff base complexes: Catalytic activity in aryl-aryl coupling reaction and antimicrobial activity
    Jayabalakrishnan, C
    Karvembu, R
    Natarajan, K
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (09): : 1535 - 1553
  • [3] Synthesis and Characterization of Aryl Acylguanidines and Their Copper(II) Complexes
    Zhou Qi
    Zhang Zhi-Jiao
    Wang Fan-Fan
    Han Li
    Zhu Cheng-Ben
    Li Hai-Pu
    Yang Ying
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (08) : 1283 - 1296
  • [4] (Phosphinito)aryl benzimidazole PCN pincer palladium(II) complexes: Synthesis, characterization and catalytic activity in C-H arylation of azoles with aryl iodides
    Wang, Cong
    Li, Yang
    Lu, Beibei
    Hao, Xin-Qi
    Gong, Jun-Fang
    Song, Mao-Ping
    [J]. POLYHEDRON, 2018, 143 : 184 - 192
  • [5] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl–aryl couplings and biological activity
    Ramasamy Karvembu
    Chinnasamy Jayabalakrishnan
    Nallasamy Dharmaraj
    Somanur V. Renukadevi
    Karuppannan Natarajan
    [J]. Transition Metal Chemistry, 2002, 27 : 631 - 638
  • [6] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl-aryl couplings and biological activity
    Karvembu, R
    Jayabalakrishnan, C
    Dharmaraj, N
    Renukadevi, SV
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2002, 27 (06) : 631 - 638
  • [7] Synthesis, characterization and catalytic activities of Zn(II) and Cd(II) complexes supported by unsymmetrical aryl thiourea ligands
    Banerjee, Indrani
    Bhattacharjee, Jayeeta
    Kumar, Ravi
    Pal, Kuntal
    Panda, Tarun K.
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2023, 649 (05):
  • [8] Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
    Huang, Wei
    Lu, Jiahui
    Fan, Qingqing
    Li, Xiaoyan
    Hinz, Alexander
    Sun, Hongjian
    [J]. NEW JOURNAL OF CHEMISTRY, 2022, 46 (16) : 7512 - 7521
  • [9] SYNTHESIS AND CHARACTERIZATION OF PALLADIUM(II) COMPLEXES WITH ARYL TELLUROLS AND DIARYL DITELLURIDES
    KHANDELWAL, BL
    KUNDU, K
    GUPTA, SK
    [J]. INORGANICA CHIMICA ACTA, 1988, 154 (02) : 183 - 188
  • [10] Nickel(ii) complexes with novel nitron-type NHC ligands: synthesis and catalytic activity in the Suzuki-Miyaura coupling of aryl chlorides
    Pyatachenko, Anastasia S.
    Chernenko, Andrey Yu.
    Soliev, Safarmurod B.
    Minyaev, Mikhail E.
    Chernyshev, Victor M.
    [J]. MENDELEEV COMMUNICATIONS, 2024, 34 (01) : 39 - 42