Pentamethylcyclopentadienylruthenium(II) Complexes: Synthesis, Characterization and Catalytic Activity in Aryl–Aryl Coupling

被引：0
|
作者：
Vettaikaranpudur G. Gnanasoundari
Karuppannan Natarajan
机构：
[1] Bharathiar University,Department of Chemistry
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Physical Chemistry; Inorganic Chemistry; Catalytic Activity; Aniline; Ruthenium;
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暂无
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学科分类号：
摘要：
Ruthenium(II) complexes of the type [Ru(PPh3)(η5-C5Me5)L] have been synthesized by the reactions of [RuCl(PPh3)2(η5-C5Me5)] with Schiff bases having the (N, O) donor atoms. The Schiff bases used in this study were prepared by condensing the appropriate aniline with salicylaldehyde or 2-hydroxy-1-naphthaldehyde in a 1:2 molar ratio respectively. The complexes were characterized by analytical, spectral (i.r., electronic and 1H-n.m.r.) data. The new complexes have been used as catalysts in aryl–aryl coupling reactions.
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页码：376 / 379
页数：3
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