Ruthenium(III) Schiff base complexes: Catalytic activity in aryl-aryl coupling reaction and antimicrobial activity

被引：18
|
作者：
Jayabalakrishnan, C [1 ]
Karvembu, R [1 ]
Natarajan, K [1 ]
机构：
[1] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2003年 / 33卷 / 09期
关键词：
D O I：
10.1081/SIM-120025439
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of several hexa-coordinated ruthenium(III) Schiff base complexes of the type [RuX(EPh3)(2)(L)] (E = P or As: X = Cl or BY; L = anion of the Schiff bases derived by the condensation of salicylaldehyde or o-hydroxyacetophenone with benzoylhydrazine or p-chlorobenzoylhydrazine) are reported. IR, EPR, electronic spectra and cyclic voltammetric data of the complexes are discussed. An octahedral geometry has been tentatively proposed for all of these complexes. The new complexes have been subjected to a catalytic activity study in the aryl-aryl Coupling reaction and also to ail antibacterial study.
引用
收藏
页码：1535 / 1553
页数：19
相关论文
共 50 条
  • [1] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl-aryl couplings and biological activity
    Karvembu, R
    Jayabalakrishnan, C
    Dharmaraj, N
    Renukadevi, SV
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2002, 27 (06) : 631 - 638
  • [2] Pentamethylcyclopentadienylruthenium(II) complexes: Synthesis, characterization and catalytic activity in aryl-aryl coupling
    Gnanasoundari, VG
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2004, 29 (04) : 376 - 379
  • [3] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl–aryl couplings and biological activity
    Ramasamy Karvembu
    Chinnasamy Jayabalakrishnan
    Nallasamy Dharmaraj
    Somanur V. Renukadevi
    Karuppannan Natarajan
    [J]. Transition Metal Chemistry, 2002, 27 : 631 - 638
  • [4] Effect of transition metal complexes on aryl-aryl coupling
    Rao, GN
    Janardhana, C
    Pasupathy, K
    Kumar, PM
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2000, 39 (02): : 151 - 153
  • [5] Pentamethylcyclopentadienylruthenium(II) Complexes: Synthesis, Characterization and Catalytic Activity in Aryl–Aryl Coupling
    Vettaikaranpudur G. Gnanasoundari
    Karuppannan Natarajan
    [J]. Transition Metal Chemistry, 2004, 29 : 376 - 379
  • [6] Synthesis, spectra, redox property and catalytic activity of ruthenium(III) Schiff base complexes
    Venkatachalam, G
    Maheswaran, S
    Ramesh, R
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2005, 44 (04): : 705 - 709
  • [7] ASYMMETRIC ARYL-ARYL COUPLING CATALYZED BY PALLADIUM(O) COMPLEXES
    ZHANG, YZ
    ZHOU, ZH
    YU, ZM
    DAI, LX
    [J]. ACTA CHIMICA SINICA, 1989, 47 (04) : 404 - 407
  • [8] New ruthenium(III) complexes with tridentate Schiff base and their catalytic activity toward oxidation of alcohols
    Saridha, K
    Karvembu, R
    Viswanathamurthi, P
    Yasodhai, S
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2005, 35 (09) : 707 - 711
  • [9] Synthesis, characterization, electrochemical, catalytic and antimicrobial activity studies of hydrazone Schiff base ruthenium(II) complexes
    Thilagavathi, N.
    Manimaran, A.
    Priya, N. Padma
    Sathya, N.
    Jayabalakrishnan, C.
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (04) : 301 - 307
  • [10] Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes
    Himmelstrup, Jonas
    Buendia, Mikkel B.
    Sun, Xing-Wen
    Kramer, Soren
    [J]. CHEMICAL COMMUNICATIONS, 2019, 55 (86) : 12988 - 12991
12345