Pentamethylcyclopentadienylruthenium(II) complexes: Synthesis, characterization and catalytic activity in aryl-aryl coupling

被引：6
|
作者：
Gnanasoundari, VG [1 ]
Natarajan, K [1 ]
机构：
[1] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
来源：
TRANSITION METAL CHEMISTRY | 2004年 / 29卷 / 04期
关键词：
D O I：
10.1023/B:TMCH.0000027449.64511.b0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium(II) complexes of the type [Ru(PPh3)(eta(5)-C5Me5) L] have been synthesized by the reactions of [RuCl(PPh3)(2)(eta(5)-C5Me5)] with Schiff bases having the (N, O) donor atoms. The Schi. bases used in this study were prepared by condensing the appropriate aniline with salicylaldehyde or 2-hydroxy-1-naphthaldehyde in a 1: 2 molar ratio respectively. The complexes were characterized by analytical, spectral (i. r., electronic and H-1-n. m. r.) data. The new complexes have been used as catalysts in aryl - aryl coupling reactions.
引用
收藏
页码：376 / 379
页数：4
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