Tetranuclear rhenium chalcochloride cluster complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Se and Te): Synthesis and structures

被引：0
|
作者：
Yu. V. Mironov
O. A. Efremova
S. S. Yarovoi
V. E. Fedorov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Russian Journal of Coordination Chemistry | 2009年 / 35卷
关键词：
Rhenium; CsCl; Cluster Anion; Cluster Core; Terminal Ligand;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The tetranuclear cluster rhenium complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Te (I) and Se (II)) with the Cl atoms as terminal ligands were obtained and structurally characterized. The structures of complexes I and II were determined by X-ray diffraction analysis. Their isostructural crystals are monoclinic; space group C2, Z = 6; a = 26.403(8) Å, b = 16.495(5) Å, c = 11.744(3) Å, β = 91.25(2)°, V = 5113(2) Å3 (I); a = 26.573(3) Å, b = 16.461(3) Å, c = 11.726(2) Å, β = 91.381(4)°, V = 5127.6(14) Å3 (II).
引用
收藏
页码：317 / 319
页数：2
相关论文
共 50 条
  • [1] Tetranuclear rhenium chalcochloride cluster complexes Cs3H[Re4Q4Cl12] • 3.33H2O (Q = Se and Te): Synthesis and structures
    Mironov, Yu. V.
    Efremova, O. A.
    Yarovoi, S. S.
    Fedorov, V. E.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (05) : 317 - 319
  • [2] Syntheses and characterizations of the new tetranuclear rhenium cluster compounds Re-4(mu(3)-Q)(4)(TeCl2)(4)Cl-8 (Q=S,Se, Te)
    Mironov, YV
    AlbrechtSchmitt, TE
    Ibers, JA
    [J]. INORGANIC CHEMISTRY, 1997, 36 (05) : 944 - &
  • [3] Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4- (Q= S, Se, Te):: synthesis and crystal structures
    Mironov, YV
    [J]. POLYHEDRON, 2000, 19 (04) : 437 - 439
  • [4] One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3
    A. S. Pronin
    A. I. Smolentsev
    Y. V. Mironov
    [J]. Russian Chemical Bulletin, 2019, 68 : 777 - 781
  • [5] One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(μ3-Q)4}(CN)12]4- (Q = S, Se, Te) using ReI3
    Pronin, A. S.
    Smolentsev, A., I
    Mironov, Y., V
    [J]. RUSSIAN CHEMICAL BULLETIN, 2019, 68 (04) : 777 - 781
  • [6] Isomerism in tetrahedral rhenium cluster complexes [Re4Q4(PMe2Ph)4X8]•nCH2Cl2 (Q = Se, X = Br; Q = Te, X = Cl, Br)
    Efremova, Olga A.
    Mironov, Yuri V.
    Brylev, Konstantin A.
    Fedorov, Vladimir E.
    Pietzsch, Hans-Juergen
    Stephan, Holger
    [J]. POLYHEDRON, 2009, 28 (14) : 2973 - 2976
  • [7] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(μ3-Q)8}(CN)6]4– (Q = S, Se, Te)
    A. S. Pronin
    S. S. Yarovoy
    A. I. Smolentsev
    Yu. V. Mironov
    [J]. Russian Journal of Coordination Chemistry, 2019, 45 : 119 - 123
  • [8] Octahedral aqua fluoride rhenium cluster complexes K[Re6S8F3(H2O)3]•7H2O, H3O[Re6Se8F3(H2O)3]•7H2O and [Re6Q8F2(H2O)4]•12H2O (Q = S, Se):: Synthesis and structure
    Mironov, Yuri V.
    Yarovoi, Spartak S.
    Naumov, Dmitrii Y.
    Simon, Arndt
    Fedorov, Vladimir E.
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (09) : 2953 - 2957
  • [9] First examples of chalcofluoride rhenium cluster complexes with cubane like anions [Re4Q4F12]4- (Q = S, Se)
    Mironov, YV
    Yarovoi, SS
    Naumov, DY
    Kuratieva, NV
    Kozlova, SG
    Simon, A
    Fedorov, VE
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (12) : 2476 - 2479
  • [10] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(3-Q)8}(CN)6]4- (Q = S, Se, Te)
    Pronin, A. S.
    Yarovoy, S. S.
    Smolentsev, A., I
    Mironov, Yu, V
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (02) : 119 - 123
12345