Tetranuclear rhenium chalcochloride cluster complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Se and Te): Synthesis and structures

被引：0

作者：

Yu. V. Mironov

O. A. Efremova

S. S. Yarovoi

V. E. Fedorov

机构：

[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division

来源：

Russian Journal of Coordination Chemistry | 2009年 / 35卷

关键词：

Rhenium; CsCl; Cluster Anion; Cluster Core; Terminal Ligand;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The tetranuclear cluster rhenium complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Te (I) and Se (II)) with the Cl atoms as terminal ligands were obtained and structurally characterized. The structures of complexes I and II were determined by X-ray diffraction analysis. Their isostructural crystals are monoclinic; space group C2, Z = 6; a = 26.403(8) Å, b = 16.495(5) Å, c = 11.744(3) Å, β = 91.25(2)°, V = 5113(2) Å3 (I); a = 26.573(3) Å, b = 16.461(3) Å, c = 11.726(2) Å, β = 91.381(4)°, V = 5127.6(14) Å3 (II).

引用

页码：317 / 319

页数：2

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