New cobalt and iron pivalate complexes with 2,2′:6′,2″-terpyridine: synthesis, structure, and magnetic properties

被引：0
|
作者：
K. L. Tokarev
M. A. Kiskin
A. A. Sidorov
G. G. Aleksandrov
V. N. Ikorskii
I. P. Suzdalev
V. M. Novotortsev
I. L. Eremenko
机构：
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
[2] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
[3] Siberian Branch of the Russian Academy of Sciences,International Tomography Center
[4] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
iron(; ) complexes; cobalt(; ) complexes; polynuclear iron(; ) complexes; carboxylate ligands; X-ray diffraction study; Mössbauer spectroscopy; magnetic properties;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The mononuclear complexes (η3-terpy)M(Piv)2·MeCN (M = Feii (3) and Coii (4), and Piv is the pivalate anion) were synthesized by the reactions of polymeric iron(ii) and cobalt(ii) pivalates with 2,2′:6′,2″-terpyridine (terpy). The oxidation of compound 3 affords the pentanuclear heterospin iron(ii,iii) complex (η3-terpy)Fe5(μ4-O)(μ3-OH)(μ-OH)2(μ-Piv)7(η1-Piv)2 (5). All compounds were characterized by X-ray diffraction.
引用
收藏
页码：1209 / 1214
页数：5
相关论文
共 50 条
  • [21] SYNTHESIS, STRUCTURE, AND TRANSITION-METAL COMPLEXES OF 4'-FERROCENYL-2,2'/6'2''-TERPYRIDINE
    FARLOW, BC
    NILE, TA
    WALSH, JL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 12 - INOR
  • [22] Synthesis and properties of the elusive ruthenium(II) complexes of 4′-cyano-2,2′:6′,2"-terpyridine
    Wang, JH
    Fang, YQ
    Hanan, GS
    Loiseau, F
    Campagna, S
    INORGANIC CHEMISTRY, 2005, 44 (01) : 5 - 7
  • [23] Synthesis and luminescence properties of platinum(II) complexes of 4′-chloro-2,2′:6′,2"-terpyridine and 4,4′,4"-trichloro-2,2′:6′,2"-terpyridine
    Hobert, SE
    Carney, JT
    Cummings, SD
    INORGANICA CHIMICA ACTA, 2001, 318 (1-2) : 89 - 96
  • [24] Chain-like and dinuclear coordination polymers in lanthanide (Nd, Eu) oxochloride complexes with 2,2′:6′,2"-terpyridine: synthesis, XRD structure and magnetic properties
    Lhoste, Jerome
    Perez-Campos, Ana
    Henry, Natacha
    Loiseau, Thierry
    Rabu, Pierre
    Abraham, Francis
    DALTON TRANSACTIONS, 2011, 40 (36) : 9136 - 9144
  • [25] Synthesis of twisted dinuclear ruthenium(II) bis(2,2′:6′,2"-terpyridine) complexes
    Wang, Kung K.
    Wen, Bo
    Petersen, Jeffrey L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [26] Synthesis and electrochemical properties of transition metal complexes of 2,2′:6′,2"-terpyridine 1,1"-dioxide
    Ito, K
    Nagata, T
    Tanaka, K
    INORGANIC CHEMISTRY, 2001, 40 (24) : 6331 - +
  • [27] Synthesis, Structure and Properties of Three Copperan Complexes Based on a Bifunctional Ligand 2,2': 6'2"-Terpyridine-4'-carboxylic Acid
    He Chun-Yu
    Yang Xiao-Qing
    Zhang Yan-Hong
    Jiang Shuang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2021, 37 (12) : 2267 - 2278
  • [28] Synthesis, structures and stability of amido gold(III) complexes with 2,2′:6′,2"-terpyridine
    Iwashita, Satoshi
    Saito, Yoshiaki
    Ohtsu, Hideki
    Tsuge, Kiyoshi
    DALTON TRANSACTIONS, 2014, 43 (42) : 15719 - 15722
  • [29] The synthesis, characterisation and cytotoxicity of bisintercalating (2,2′:6′,2"-terpyridine)platinum(II) complexes
    Harper, Benjamin W. J.
    Aldrich-Wright, Janice R.
    DALTON TRANSACTIONS, 2015, 44 (01) : 87 - 96
  • [30] LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE
    CONSTABLE, EC
    THOMPSON, AMWC
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (20): : 2947 - 2950
12345