New cobalt and iron pivalate complexes with 2,2′:6′,2″-terpyridine: synthesis, structure, and magnetic properties

被引：0
|
作者：
K. L. Tokarev
M. A. Kiskin
A. A. Sidorov
G. G. Aleksandrov
V. N. Ikorskii
I. P. Suzdalev
V. M. Novotortsev
I. L. Eremenko
机构：
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
[2] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
[3] Siberian Branch of the Russian Academy of Sciences,International Tomography Center
[4] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
iron(; ) complexes; cobalt(; ) complexes; polynuclear iron(; ) complexes; carboxylate ligands; X-ray diffraction study; Mössbauer spectroscopy; magnetic properties;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The mononuclear complexes (η3-terpy)M(Piv)2·MeCN (M = Feii (3) and Coii (4), and Piv is the pivalate anion) were synthesized by the reactions of polymeric iron(ii) and cobalt(ii) pivalates with 2,2′:6′,2″-terpyridine (terpy). The oxidation of compound 3 affords the pentanuclear heterospin iron(ii,iii) complex (η3-terpy)Fe5(μ4-O)(μ3-OH)(μ-OH)2(μ-Piv)7(η1-Piv)2 (5). All compounds were characterized by X-ray diffraction.
引用
收藏
页码：1209 / 1214
页数：5
相关论文
共 50 条
  • [41] Crystal structures and fluorescence properties of lanthanide complexes prepared with 2,2′-biphenyldicarboxylic acid and 2,2′:6′,2"-terpyridine
    Xie Hongzhen
    Lu Guanzhong
    JOURNAL OF RARE EARTHS, 2013, 31 (06) : 639 - 644
  • [42] The photophysical properties of hybrid metal complexes containing both 2,2′-bipyridine and 2,2′:6′,2"-terpyridine units
    Harriman, A
    Hissler, M
    Khatyr, A
    Ziessel, R
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (05) : 955 - 959
  • [43] Synthesis and structural characterization of lanthanide metal complexes by 2-fluorobenzoic acid with 2,2′:6′,2"-terpyridine, and their fluorescence properties
    Geng, Shuo
    Ren, Ning
    Shu-Mei He
    Jian-Jun Zhang
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1252
  • [44] Metal complexes of 4′-(3-phenylpropoxy)-2,2′:6′,2"-terpyridine and 4′-(3-propoxy)-2,2′:6′,2"-terpyridine
    Liu, XM
    McInnes, EJL
    Kilner, CA
    Thornton-Pett, M
    Halcrow, MA
    POLYHEDRON, 2001, 20 (22-23) : 2889 - 2900
  • [45] Synthesis, Structure and Photoluminescence Properties of Cd and Cd-Ln Pentafluorobenzoates with 2,2′:6′,2′-Terpyridine Derivatives
    Shmelev, Maxim A.
    Voronina, Julia K.
    Evtyukhin, Maxim A.
    Dolgushin, Fedor M.
    Varaksina, Evgenia A.
    Taydakov, Ilya, V
    Sidorov, Aleksey A.
    Eremenko, Igor L.
    Kiskin, Mikhail A.
    INORGANICS, 2022, 10 (11)
  • [46] STUDIES OF SOME BINUCLEAR OXYGEN-BRIDGE COMPLEXES OF IRON(3) - NEW IRON(3)-2,2',2''-TERPYRIDINE COMPLEXES
    REIFF, WM
    BAKER, WA
    ERICKSON, NE
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (18) : 4794 - &
  • [47] Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4′-chloro-2,2′:6′,2"-terpyridine
    Zhang, Guoqi
    Tan, Jiawen
    Zhang, Yuan Zhuo
    Ta, Christine
    Sanchez, Stephanie
    Cheng, Shu-Yuan
    Golen, James A.
    Rheingold, Arnold L.
    INORGANICA CHIMICA ACTA, 2015, 435 : 147 - 152
  • [48] COLORIMETRIC DETERMINATION OF COBALT WITH 2,2',2''-TERPYRIDINE
    MILLER, RR
    BRANDT, WW
    ANALYTICAL CHEMISTRY, 1954, 26 (12) : 1968 - 1969
  • [49] Synthesis, structure and redox properties of new cobalt(II) and nickel(II) complexes with 6-ferrocenyl-2,2′-bipyridyl
    Goldberg, Anna
    Kiskin, Mikhail
    Grinberg, Vitali
    Kozyukhin, Sergey
    Bogomyakov, Artem
    Utepova, Irina
    Sidorov, Aleksey
    Chupakhin, Oleg
    Eremenko, Igor
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (13) : 2607 - 2610
  • [50] Crystal Structure Analysis of Two Chloro(2,2′:6′,2″-terpyridine)gold(III) Complexes
    Vivian Gomez
    Mark C. Hardwick
    Christine Hahn
    Journal of Chemical Crystallography, 2012, 42 : 824 - 831
12345