Synthesis and electrochemical properties of transition metal complexes of 2,2′:6′,2"-terpyridine 1,1"-dioxide

被引：11
|
作者：
Ito, K
Nagata, T [1 ]
Tanaka, K
机构：
[1] Japan Sci & Technol Corp, JST, CREST, Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Grad Univ Adv Studies, Dept Struct Mol Sci, Okazaki, Aichi 4448585, Japan
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 24期
关键词：
D O I：
10.1021/ic010883a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of a series of first-row transition metal complexes of 2,2':6',2''-terpyridine 1,1''-dioxide (terpyO(2)) are reported. Four new bis complexes [M(terpyO(2))]X-2 (M = Mn(II), Fe(II), Co(II), and Ni(II); X = ClO4- and BF4-) and one mono complex [Cu(terpyO(2))(H2O)](ClO4)(2) were isolated and characterized, and electrochemical properties were examined. [GRAPHICS]
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页码：6331 / +
页数：4
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