Investigation of La0.75Sr0.25Cr0.5Mn0.5O3-δ–Ag composite anodes for solid oxide fuel cells obtained via a low-temperature sintering process

被引:0
|
作者
Shoucheng He
Hailu Dai
Xiaowei Chen
Qingle Shi
Zetian Tao
机构
[1] Yancheng Institute of Technology,School of Materials Science and Engineering
来源
Ionics | 2020年 / 26卷
关键词
Solid oxide fuel cell; Perovskite anode; Low-temperature sintering; Electrical conductivity; Electrochemical performance;
D O I
暂无
中图分类号
学科分类号
摘要
La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM) anodes incorporated with Ag paste (AP) sintered at a relatively low temperature of 900 °C were evaluated. The results of electrochemical impedance spectroscopy displayed that the optimal electrochemical performance was acquired by incorporating 40 wt% Ag paste into the LSCM matrix. The electrical conductivity of LSCM–40AP at 800 °C in air and H2 was 192 S cm−1 and 9.96 S cm−1, respectively. The maximum power density of the cell with LSCM–40AP at 800 °C exhibited a considerable increase by a factor of 1.6, when compared with the cell with pure LSCM. The durability of the single cell with the LSCM–40AP anode was analyzed. The result revealed that the cell voltage slightly reduced from 0.67 to 0.64 V at a constant current density of 0.25 A cm−2 after a 100 h test, indicating good long-term stability of the anode sintered at 900 °C.
引用
收藏
页码:6225 / 6232
页数:7
相关论文
共 50 条
  • [41] Ru exsolution in substituted La0.75Sr0.25Cr0.5Mn0.5O3-δ compound as anode material for an IT-SOFCs
    Thommy, L.
    Benamira, M.
    Jardiel, T.
    Gunes, V.
    Joubert, O.
    Caldes, M. T.
    MATERIALS CHEMISTRY AND PHYSICS, 2021, 268
  • [42] Catalytic performance of Cu-Ni/La0.75Sr0.25Cr0.5Mn0.5O3-δ for dry methane reforming
    Liu, Hui
    Yu, Jie
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2022, 46 (08) : 10522 - 10534
  • [43] Efficient carbon dioxide electrolysis with metal nanoparticles loaded La0.75Sr0.25Cr0.5Mn0.5O3-δ cathodes
    Zhu, Changli
    Hou, Linxi
    Li, Shisong
    Gan, Lizhen
    Xie, Kui
    JOURNAL OF POWER SOURCES, 2017, 363 : 177 - 184
  • [44] Co-electrolysis of steam and CO2 in a solid oxide electrolysis cell with La0.75Sr0.25Cr0.5Mn0.5O3-δ -Cu ceramic composite electrode
    Xing, Ruimin
    Wang, Yarong
    Zhu, Yongqiang
    Liu, Shanhu
    Jin, Chao
    JOURNAL OF POWER SOURCES, 2015, 274 : 260 - 264
  • [45] Effect of Ce0.8Sm0.2O1.9 interlayer on the electrochemical performance of La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Sm0.2O1.9 composite anodes for intermediate-temperature solid oxide fuel cells
    He, Shoucheng
    Chen, Han
    Li, Ruifeng
    Ge, Lin
    Guo, Lucun
    JOURNAL OF POWER SOURCES, 2014, 253 : 187 - 192
  • [46] Potential oscillation of methane oxidation reaction on (La0.75Sr0.25)(Cr0.5Mn0.5)O3 electrodes of solid oxide fuel cells
    Wang, Wei
    Zhang, Lan
    Jian, San Ping
    JOURNAL OF POWER SOURCES, 2008, 178 (01) : 92 - 96
  • [47] La0.75Sr0.25Cr0.5Mn0.5O3-δ+Cu composite anode running on H2 and CH4 fuels
    Wan, J.
    Zhu, J. H.
    Goodenough, J. B.
    SOLID STATE IONICS, 2006, 177 (13-14) : 1211 - 1217
  • [48] Effects of Ti doping on the electrochemical performance of (La0.75Sr0.25)(Mn0.5Cr0.5)O3-δ anode for solid oxide fuel cells
    Karim, Afizul H.
    Abdalla, Abdalla M.
    Park, Jun-Y
    Petra, Pg Mohd, I
    Azad, Abul K.
    PROCESSING AND APPLICATION OF CERAMICS, 2019, 13 (04) : 342 - 348
  • [49] Preparation and Performance Study of La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Gd0.2O2-δ Gradient Composite Cathode for Solid Oxide Electrolysis Cell
    Xie, Yilin
    Kong, Jiangrong
    Pan, Di
    Liu, Xinnan
    Zhou, Tao
    Xiyou Jinshu/Chinese Journal of Rare Metals, 2021, 45 (11): : 1343 - 1351
  • [50] Sr0.75Y0.25Co0.5Mn0.5O3-y Perovskite Cathode for Solid Oxide Fuel Cells
    Burmistrov, Ilya
    Drozhzhin, Oleg A.
    Istomin, Sergey Ya.
    Sinitsyn, Vitaly V.
    Antipov, Eugeny V.
    Bredikhin, Sergey I.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (10) : B1212 - B1217