Investigation of La0.75Sr0.25Cr0.5Mn0.5O3-δ–Ag composite anodes for solid oxide fuel cells obtained via a low-temperature sintering process

被引:0
|
作者
Shoucheng He
Hailu Dai
Xiaowei Chen
Qingle Shi
Zetian Tao
机构
[1] Yancheng Institute of Technology,School of Materials Science and Engineering
来源
Ionics | 2020年 / 26卷
关键词
Solid oxide fuel cell; Perovskite anode; Low-temperature sintering; Electrical conductivity; Electrochemical performance;
D O I
暂无
中图分类号
学科分类号
摘要
La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM) anodes incorporated with Ag paste (AP) sintered at a relatively low temperature of 900 °C were evaluated. The results of electrochemical impedance spectroscopy displayed that the optimal electrochemical performance was acquired by incorporating 40 wt% Ag paste into the LSCM matrix. The electrical conductivity of LSCM–40AP at 800 °C in air and H2 was 192 S cm−1 and 9.96 S cm−1, respectively. The maximum power density of the cell with LSCM–40AP at 800 °C exhibited a considerable increase by a factor of 1.6, when compared with the cell with pure LSCM. The durability of the single cell with the LSCM–40AP anode was analyzed. The result revealed that the cell voltage slightly reduced from 0.67 to 0.64 V at a constant current density of 0.25 A cm−2 after a 100 h test, indicating good long-term stability of the anode sintered at 900 °C.
引用
收藏
页码:6225 / 6232
页数:7
相关论文
共 50 条
  • [21] Cu(Pd)-impregnated La0.75Sr0.25Cr0.5Mn0.5O3-δ anodes for direct utilization of methane in SOFC
    Lu, X. C.
    Zhu, J. H.
    SOLID STATE IONICS, 2007, 178 (25-26) : 1467 - 1475
  • [22] La0.75Sr0.25Cr0.5Mn0.5O3-δ-Ce0.8Gd0.2O1.9 composite electrodes as anodes in LaGaO3-based direct carbon solid oxide fuel cells
    CHEN Tian-yu
    XIE Yong-min
    LU Zhi-bin
    WANG Liang
    CHEN Zhe-qin
    ZHONG Xiao-cong
    LIU Jia-ming
    WANG Rui-xiang
    XU Zhi-feng
    OUYANG Shao-bo
    JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2022, 29 (06) : 1788 - 1798
  • [23] Ni/SDC Nanoparticles Modified La0.75Sr0.25Cr0.5Fe0.5O3-δ as Anodes for Solid Oxide Fuel Cells
    Zhu, Xingbao
    Lue, Zhe
    Wei, Bo
    Chen, Kongfa
    Liu, Mingliang
    Huang, Xiqiang
    Su, Wenhui
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2009, 12 (12) : B161 - B164
  • [24] Synthesis of nanoparticles of La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM) perovskite by solution combustion method for solid oxide fuel cell application
    Raza, M. A.
    Rahman, I. Z.
    Beloshapkin, S.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 485 (1-2) : 593 - 597
  • [25] Regeneration of sulfur poisoned La0.75Sr0.25Cr0.5Mn0.5O3-δ anode of solid oxide fuel cell using electrochemical oxidative method
    Li, Yiqian
    Na, Liyuan
    Lu, Zhe
    Jiang, Zishi
    ELECTROCHIMICA ACTA, 2019, 304 : 342 - 349
  • [26] Sulfur poisoning and the regeneration of the solid oxide fuel cell with metal catalyst-impregnated La0.75Sr0.25Cr0.5Mn0.5O3-δ anode
    Li, Yiqian
    Na, Liyuan
    Lu, Zhe
    Li, Shuxia
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (31) : 15650 - 15657
  • [27] La0.75Sr0.25Cr0.5Mn0.5O3 as hydrogen electrode for solid oxide electrolysis cells
    Jin, Chao
    Yang, Chenghao
    Zhao, Fei
    Cui, Daan
    Chen, Fanglin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (05) : 3340 - 3346
  • [28] Anodic performance and intermediate temperature fuel cell testing of La0.75Sr0.25Cr0.5Mn0.5O3-δ at lanthanum gallate electrolytes
    Peña-Martínez, J
    Marrero-López, D
    Ruiz-Morales, JC
    Savaniu, C
    Núñez, P
    Irvine, JTS
    CHEMISTRY OF MATERIALS, 2006, 18 (04) : 1001 - 1006
  • [29] GDC-impregnated, (La0.75Sr0.25)(Cr0.5Mn0.5)O3 anodes for direct utilization of methane in solid oxide fuel cells
    Jiang, SP
    Chen, XJ
    Chan, SH
    Kwok, JT
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (05) : A850 - A856
  • [30] Development of (La0.75Sr0.25)(Cr0.5Mn0.5)O3 Cathodes of Solid Oxide Fuel Cells By Gelcasting Technique
    Jiang, S. P.
    Zhang, L.
    Cheng, C. S.
    Zhang, Y.
    SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01): : 1081 - 1088