Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes

被引：183
|
作者：
Battin-Leclerc, Frederique [1 ]
Herbinet, Olivier [1 ]
Glaude, Pierre-Alexandre [1 ]
Fournet, Rene [1 ]
Zhou, Zhongyue [2 ]
Deng, Liulin [2 ]
Guo, Huijun [2 ]
Xie, Mingfeng [2 ]
Qi, Fei [2 ]
机构：
[1] Nancy Univ, CNRS, Lab React & Genie Procedes, ENSIC, F-54001 Nancy, France
[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 18期
基金：
欧洲研究理事会;
关键词：
hydroperoxides; mass spectrometry; molecular beams; oxidation; photoionization; N-HEPTANE; HYDROCARBONS; AUTOIGNITION; COMBUSTION; MIXTURES; PRESSURE; IGNITION; REACTOR; MODEL;
D O I：
10.1002/anie.200906850
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical equation presented) Intermediate detected: The design of internal combustion engines relies on a good understanding of the mechanism of the auto-ignition of hydrocarbons. A key assumption of this mechanism, which was commonly accepted but never proven, has now been experimentally demonstrated: the formation of ketohydroperoxides has been observed under conditions close to those actually observed before the auto-ignition. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：3169 / 3172
页数：4
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