Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes

被引：183

作者：

Battin-Leclerc, Frederique ^{[1
]}

Herbinet, Olivier ^{[1
]}

Glaude, Pierre-Alexandre ^{[1
]}

Fournet, Rene ^{[1
]}

Zhou, Zhongyue ^{[2
]}

Deng, Liulin ^{[2
]}

Guo, Huijun ^{[2
]}

Xie, Mingfeng ^{[2
]}

Qi, Fei ^{[2
]}

机构：

[1] Nancy Univ, CNRS, Lab React & Genie Procedes, ENSIC, F-54001 Nancy, France

[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 18期

基金：

欧洲研究理事会;

关键词：

hydroperoxides; mass spectrometry; molecular beams; oxidation; photoionization; N-HEPTANE; HYDROCARBONS; AUTOIGNITION; COMBUSTION; MIXTURES; PRESSURE; IGNITION; REACTOR; MODEL;

D O I：

10.1002/anie.200906850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical equation presented) Intermediate detected: The design of internal combustion engines relies on a good understanding of the mechanism of the auto-ignition of hydrocarbons. A key assumption of this mechanism, which was commonly accepted but never proven, has now been experimentally demonstrated: the formation of ketohydroperoxides has been observed under conditions close to those actually observed before the auto-ignition. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3169 / 3172

页数：4

共 50 条

[21] LOW-TEMPERATURE OXIDATION CATALYSTS
UPCHURCH, BT
SCHRYER, DR
WOOD, GM
KIELIN, EJ
BROWN, KG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 66 - CATL
[22] LOW-TEMPERATURE OXIDATION OF CARBON
LEWIS, WK
GILLILAND, ER
PAXTON, RR
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1954, 46 (06): : 1327 - 1331
[23] LOW-TEMPERATURE OXIDATION OF SILICON
MADANI, MR
AJMERA, PK
ELECTRONICS LETTERS, 1988, 24 (14) : 856 - 857
[24] Low-temperature oxidation of acetaldehyde
Aivazov, BV
ACTA PHYSICOCHIMICA URSS, 1938, 8 : 617 - 622
[25] Low-Temperature Oxidation of Methane
Farrauto, Robert J.
SCIENCE, 2012, 337 (6095) : 659 - 660
[26] LOW-TEMPERATURE FUNCTIONALIZATION OF ALKANES WITH HOMOGENEOUS PLATINUM CATALYSTS
HORVATH, IT
KISS, G
COOK, RA
MILLAR, JM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 436 - INOR
[27] Experimental and kinetic modeling study of low-temperature oxidation of n -pentane
Liu, Bingzhi
Di, Qimei
Lailliau, Maxence
Belhadj, Nesrine
Dagaut, Philippe
Wang, Zhandong
COMBUSTION AND FLAME, 2023, 254
[28] Experimental and numerical low-temperature oxidation study of ethanol and dimethyl ether
Herrmann, Friederike
Jochim, Bernhard
Oswald, Patrick
Cai, Liming
Pitsch, Heinz
Kohse-Hoeinghaus, Katharina
COMBUSTION AND FLAME, 2014, 161 (02) : 384 - 397
[29] Experimental research on low-temperature oxidation characteristics of lignite in inner Mongolia
Yang, Hongmin
Wang, Zhaofeng
Progress in Mining Science and Safety Technology, Pts A and B, 2007, : 1914 - 1920
[30] Developing the Low-Temperature Oxidation Mechanism of Cyclopentane: An Experimental and Theoretical Study
Shi, Zaifa
Chen, Shanjun
Chen, Jun
Tang, Zichao
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (08) : e202200256

← 1 2 3 4 5 →