Kinetics and mechanism of osmium(VIII) catalysed oxidation of L-arginine by hexacyanoferrate(III) in alkaline medium

被引：0

作者：

Sridevi, Garapati ^{[1
]}

Annapurna, Nowduri ^{[1
]}

Vani, Parvataneni ^{[1
]}

机构：

[1] Andhra Univ, Dept Inorgan & Analyt Chem, Visakhapatnam 500003, Andhra Pradesh, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2010年 / 87卷 / 07期

关键词：

Oxidation of L-arginine; hexacyanoferrate(III); osmium(VIII); CHLORAMINE-T; HISTIDINE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The osmium(VIII) catalysed reaction between L-arginine and hexacyanoferrate(III) (HCF(III) in alkaline medium has a stoichiometry of 1 : 2 with zero order dependence on [HCF(III)]. The reaction is first order with respect to [catalyst], [alkali] and fractional order with respect to [substrate]. No effect of added product was observed.

引用

页码：773 / 778

页数：6

共 50 条

[41] Osmium(VIII)-catalysed Oxidation of Dimethylamine by Periodate in Aqueous Alkaline Medium
Hiremath, S. C.
Chimatadar, S. A.
Raju, J. R.
Journal of the Indian Chemical Society, 73 (06):
[42] Osmium(VIII)-catalysed oxidation of dimethylamine by periodate in aqueous alkaline medium
Hiremath, SC
Chimatadar, SA
Raju, JR
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1996, 73 (06) : 279 - 281
[43] Kinetics and mechanism of oxidation of L-arginine by diperiodato-nickelate(IV) in aqueous alkaline medium
Kembhavi, MR
Harihar, AL
Nandibewoor, ST
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1999, 76 (02) : 79 - 82
[44] A kinetic and mechanistic study on the oxidation of arginine and lysine by hexacyanoferrate(III) catalysed by iridium(III) in aqueous alkaline medium
Goel, Anjali
Sharma, Ruchi
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2012, 89 (09) : 1191 - 1196
[45] MECHANISM OF RU(III)-CATALYSED OXIDATION OF CYCLOPENTANOL BY ALKALINE HEXACYANOFERRATE(III)
SINGH, RN
SINGH, HS
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1978, 16 (02): : 145 - 147
[46] KINETICS AND MECHANISM OF OS(VIII) CATALYZED OXIDATION OF CROTONIC ACID BY ALKALINE HEXACYANOFERRATE(III)
KUMAR, S
MATHUR, PC
POLISH JOURNAL OF CHEMISTRY, 1979, 53 (10) : 2061 - 2067
[47] KINETICS AND MECHANISM OF OS(VIII) CATALYZED OXIDATION OF MALATE ION BY ALKALINE HEXACYANOFERRATE (III)
SONI, GC
MENGHANI, GD
TETRAHEDRON, 1972, 28 (22) : 5567 - &
[48] Investigation of kinetics and mechanism of oxidation of acetoacetanilide in alkaline medium using hexacyanoferrate(III)
Bagalkoti, Jyoti
Nandibewoor, Sharanappa T.
MONATSHEFTE FUR CHEMIE, 2019, 150 (08): : 1469 - 1478
[49] Investigation of kinetics and mechanism of oxidation of acetoacetanilide in alkaline medium using hexacyanoferrate(III)
Jyoti Bagalkoti
Sharanappa T. Nandibewoor
Monatshefte für Chemie - Chemical Monthly, 2019, 150 : 1469 - 1478
[50] Kinetics and mechanism of the oxidation of adonitol by hexacyanoferrate(III) ion in aqueous alkaline medium
Quadri, NF
Patel, NT
ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (03) : 1724 - 1728

← 1 2 3 4 5 →