Kinetics and mechanism of osmium(VIII) catalysed oxidation of L-arginine by hexacyanoferrate(III) in alkaline medium

被引：0
|
作者：
Sridevi, Garapati [1 ]
Annapurna, Nowduri [1 ]
Vani, Parvataneni [1 ]
机构：
[1] Andhra Univ, Dept Inorgan & Analyt Chem, Visakhapatnam 500003, Andhra Pradesh, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2010年 / 87卷 / 07期
关键词：
Oxidation of L-arginine; hexacyanoferrate(III); osmium(VIII); CHLORAMINE-T; HISTIDINE;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The osmium(VIII) catalysed reaction between L-arginine and hexacyanoferrate(III) (HCF(III) in alkaline medium has a stoichiometry of 1 : 2 with zero order dependence on [HCF(III)]. The reaction is first order with respect to [catalyst], [alkali] and fractional order with respect to [substrate]. No effect of added product was observed.
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收藏
页码：773 / 778
页数：6
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