Kinetics and mechanism of osmium(VIII) catalysed oxidation of L-arginine by hexacyanoferrate(III) in alkaline medium

被引：0

作者：

Sridevi, Garapati ^{[1
]}

Annapurna, Nowduri ^{[1
]}

Vani, Parvataneni ^{[1
]}

机构：

[1] Andhra Univ, Dept Inorgan & Analyt Chem, Visakhapatnam 500003, Andhra Pradesh, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2010年 / 87卷 / 07期

关键词：

Oxidation of L-arginine; hexacyanoferrate(III); osmium(VIII); CHLORAMINE-T; HISTIDINE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The osmium(VIII) catalysed reaction between L-arginine and hexacyanoferrate(III) (HCF(III) in alkaline medium has a stoichiometry of 1 : 2 with zero order dependence on [HCF(III)]. The reaction is first order with respect to [catalyst], [alkali] and fractional order with respect to [substrate]. No effect of added product was observed.

引用

页码：773 / 778

页数：6

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