Sol-gel preparation of zinc sulfide using organic dithiols

被引：23
|
作者：
Donahue, EJ [1 ]
Roxburgh, A [1 ]
Yurchenko, M [1 ]
机构：
[1] Long Isl Univ, Dept Chem, Brooklyn, NY 11201 USA
来源：
MATERIALS RESEARCH BULLETIN | 1998年 / 33卷 / 02期
基金：
美国国家科学基金会;
关键词：
chalcogenides; sol-gel chemistry; semiconductors;
D O I：
10.1016/S0025-5408(97)00232-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Zinc sulfide is an important electro-optic material that is useful as an infrared window and, when doped, as a phosphor or as the basis for an LED. This paper presents a solution-based method for preparing the material through sol-gel processing. Ethanedithiol and zinc chloride were mixed and the resulting sol was heated in a three-step process, producing crystalline wurtzite. Analysis of the sol and its decomposition indicates the following reaction mechanism: nZnCl(2)+HSCH2CH2SH-->-(ZnSCH2CH2S)(n)-+2nHCl up arrow. (C) 1998 Elsevier Science Ltd.
引用
收藏
页码：323 / 329
页数：7
相关论文
共 50 条
  • [41] The preparation of organic/inorganic conducting polymer composite films using in-situ sol-gel process
    Lee, Y
    Kim, J
    Son, Y
    POLYMER-KOREA, 1999, 23 (03) : 443 - 449
  • [42] Preparation of Organic–Inorganic Multifunctional Nanocomposite Coating via Sol-Gel Routes
    Haoying Li
    Yunfa Chen
    Chengxiang Ruan
    Weimin Gao
    Yusheng Xie
    Journal of Nanoparticle Research, 2001, 3 : 157 - 160
  • [43] Sol-gel preparation of thick titania coatings aided by organic binder materials
    Chen, W
    Zhang, JY
    Fang, Q
    Li, S
    Wu, JX
    Li, FQ
    Jiang, K
    SENSORS AND ACTUATORS B-CHEMICAL, 2004, 100 (1-2) : 195 - 199
  • [44] Preparation and characterization of photopolymerizable organic–inorganic hybrid materials by the sol-gel method
    Sevim Karataş
    Zuhal Hoşgör
    Nilhan-Kayaman Apohan
    Atilla Güngör
    Journal of Polymer Research, 2010, 17 : 247 - 254
  • [45] Sol-gel preparation of transparent zinc oxide films with highly preferential crystal orientation
    Li, HX
    Wang, JY
    Liu, H
    Yang, CH
    Xu, HY
    Li, X
    Cui, HM
    VACUUM, 2004, 77 (01) : 57 - 62
  • [46] Sol-gel preparation and infrared radiation property of zinc-substituted cordierite ceramics
    Wang, Xu
    Jiao, Baoxiang
    Zhang, Xia
    Luo, Juhua
    Guan, Hao
    ADVANCES IN MATERIALS AND MATERIALS PROCESSING, PTS 1-3, 2013, 652-654 : 316 - +
  • [47] PREPARATION BY A SOL-GEL PROCESS OF BOROSILICATE CLASSES CONTAINING MICROCRYSTALS OF TELLURIUM AND ZINC TELLURIDE
    LI, GM
    NOGAMI, M
    ABE, Y
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (11) : 2885 - 2888
  • [48] Effect of Catalyst on Preparation of YAG Sol by the Sol-Gel Process
    Guo Xingzhong
    Zhu Xiaoyi
    Zhang Lingjie
    Yang Hui
    RARE METAL MATERIALS AND ENGINEERING, 2010, 39 : 228 - 231
  • [49] PREPARATION OF Bi－SYSTEM SUPERCONDUCTOR USING SOL－GEL METHOD
    Yin Zhoulan(Department of Chemistry
    Journal of Central South University of Technology(English Edition), 1996, (02) : 41 - 44
  • [50] Preparation of barium hexaferrite nanopowders by the sol-gel method, using goethite
    Mozaffari, M.
    Taheri, M.
    Amighian, J.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (09) : 1285 - 1289
12345