Sol-gel preparation of zinc sulfide using organic dithiols

被引：23
|
作者：
Donahue, EJ [1 ]
Roxburgh, A [1 ]
Yurchenko, M [1 ]
机构：
[1] Long Isl Univ, Dept Chem, Brooklyn, NY 11201 USA
来源：
MATERIALS RESEARCH BULLETIN | 1998年 / 33卷 / 02期
基金：
美国国家科学基金会;
关键词：
chalcogenides; sol-gel chemistry; semiconductors;
D O I：
10.1016/S0025-5408(97)00232-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Zinc sulfide is an important electro-optic material that is useful as an infrared window and, when doped, as a phosphor or as the basis for an LED. This paper presents a solution-based method for preparing the material through sol-gel processing. Ethanedithiol and zinc chloride were mixed and the resulting sol was heated in a three-step process, producing crystalline wurtzite. Analysis of the sol and its decomposition indicates the following reaction mechanism: nZnCl(2)+HSCH2CH2SH-->-(ZnSCH2CH2S)(n)-+2nHCl up arrow. (C) 1998 Elsevier Science Ltd.
引用
收藏
页码：323 / 329
页数：7
相关论文
共 50 条
  • [31] Immobilization of a thermostable enzyme using a sol-gel preparation method
    Ariga, O
    Suzuki, T
    Sano, Y
    Murakami, Y
    JOURNAL OF FERMENTATION AND BIOENGINEERING, 1996, 82 (04): : 341 - 345
  • [32] Encapsulation of zinc tetrasulfophthalocyanine in sol-gel materials
    Zhan, H
    Chen, W
    Chen, J
    Wang, M
    MATERIALS LETTERS, 2003, 57 (9-10) : 1483 - 1488
  • [33] Characterization of cerium-doped zinc sulfide thin films synthesized by sol-gel method
    Tounsi, A.
    Khalfi, R.
    Talantikite-Touati, D.
    Merzouk, H.
    Souici, A.
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2022, 128 (04):
  • [34] Dimerization of zinc tetrasulfophthalocyanine in sol-gel process
    Zhan, HB
    Chen, WZ
    Chen, JC
    Wang, MQ
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 100 (02): : 119 - 123
  • [35] STUDY ON PREPARATION OF ORGANIC/INORGANIC HYBRID BIOMATERIALS THROUGH SOL-GEL PROCESS
    Zou Han
    Chen Hongmei (Institute of Biomedical Engineering
    ChineseJournalofBiomedicalEngineering(EnglishEdition), 1997, (04) : 257 - 276
  • [36] PREPARATION OF AMORPHOUS SILICAS DOPED WITH ORGANIC-MOLECULES BY THE SOL-GEL PROCESS
    MAKISHIMA, A
    TANI, T
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1986, 69 (04) : C72 - C74
  • [37] Preparation of RF organic aerogels and carbon aerogels by alcoholic sol-gel process
    Qin, GT
    Guo, SC
    CARBON, 2001, 39 (12) : 1935 - 1937
  • [38] Sol-gel processing of germanium sulfide based films
    Depto. Engenharia de Materiais/INESC, Inst. Sup. Tecn., Av. Rovisco P., Lisbon, Portugal
    J Non Cryst Solids, (25-30):
  • [39] Sol-gel processing of germanium sulfide based films
    Martins, O
    Xu, J
    Almeida, RM
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 256 : 25 - 30
  • [40] Sol-gel derived germanium sulfide planar waveguides
    Xu, J
    Almeida, RM
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2000, 3 (5-6) : 339 - 344
12345