Catalytic oxidation of alkenes with ruthenium(II) perchlorate complexes

被引：10
|
作者：
Kanmani, AS [1 ]
Vancheesan, S [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 125卷 / 2-3期
关键词：
ruthenium(II) perchlorate; homogeneous; catalyst; cyclohexene; oxidation;
D O I：
10.1016/S1381-1169(97)00087-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ruthenium(II) perchlorate complexes, [Ru(dppm)(3)(ClO4)]ClO4, 1, Ru(dppe)(3)(ClO4)]ClO4, 2, [Ru(dpae)(3)(ClO4)]ClO4, 3, catalyse the oxidation of cyclohexene in the presence of cumene hydroperoxide (CHP) under homogeneous liquid phase. The products of oxidation are 2-cyclohexen-1-ol and 2-cyclohexenone. Linear alkenes like 1-heptene and 1-octene are not efficiently oxidised under these conditions. Solvent influences the rate of oxidation considerably. N-methylmorpholine-N-oxide (NMO) and CHP are compared for their oxidising ability. (C) 1997 Elsevier Science B.V.
引用
下载
收藏
页码：127 / 134
页数：8
相关论文
共 50 条
  • [41] Catalytic Water Oxidation by Ruthenium(II) Quaterpyridine (qpy) Complexes: Evidence for Ruthenium(III) qpy-N,N′′′-dioxide as the Real Catalysts
    Liu, Yingying
    Ng, Siu-Mui
    Yiu, Shek-Man
    Lam, William W. Y.
    Wei, Xi-Guang
    Lau, Kai-Chung
    Lau, Tai-Chu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (52) : 14468 - 14471
  • [42] Aziridination of alkenes promoted by iron or ruthenium complexes
    Damiano, Caterina
    Intrieri, Daniela
    Gallo, Emma
    INORGANICA CHIMICA ACTA, 2018, 470 : 51 - 67
  • [43] Selective catalytic oxidation of alkenes employing homobinuclear manganese(II) catalysts with TBHP
    Kilic, Yalcin
    Kani, Ibrahim
    POLYHEDRON, 2018, 141 : 352 - 359
  • [44] CATALYTIC ACTIVITY OF POLYMER-SUPPORTED COBALT(II) CATALYSTS IN THE OXIDATION OF ALKENES
    Pielichowski, Jan
    Kowalski, Grzegorz
    Zaikov, Gennady
    CHEMISTRY & CHEMICAL TECHNOLOGY, 2011, 5 (03): : 303 - 308
  • [45] SYNTHESIS AND CATALYTIC PROPERTIES OF SOME CARBONYLTRIPHENYLPHOSPHINE-RUTHENIUM(II) COMPLEXES
    JAMES, BR
    MARKHAM, LD
    HUI, BC
    REMPEL, GL
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (21): : 2247 - 2252
  • [46] Synthesis and catalytic applications of ruthenium(II)-phosphino-oxime complexes
    Francos, Javier
    Menendez-Rodriguez, Lucia
    Tomas-Mendivil, Eder
    Crochet, Pascale
    Cadierno, Victorio
    RSC ADVANCES, 2016, 6 (45): : 39044 - 39052
  • [47] FACTORS DETERMINING CATALYTIC ACTIVITY OF POLYCARBOXYLATE BOUND RUTHENIUM (II) COMPLEXES
    BRACA, G
    CIARDELLI, F
    SBRANA, G
    VALENTINI, G
    CHIMICA & L INDUSTRIA, 1977, 59 (11): : 766 - 768
  • [48] Structural, Electronic, and Catalytic Modulation of Chelating Pyridylideneamide Ruthenium(II) Complexes
    Navarro, Miquel
    Segarra, Candela
    Pfister, Tim
    Albrecht, Martin
    ORGANOMETALLICS, 2020, 39 (13) : 2383 - 2391
  • [49] Stereospecific and regioselective catalytic epoxidation of alkenes by a novel ruthenium(II) complex under aerobic conditions
    Kesavan, V
    Chandrasekaran, S
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (21): : 3115 - 3116
  • [50] Catalytic dehalogenation of aryl chlorides mediated by ruthenium(II) phosphine complexes
    Cucullu, ME
    Nolan, SP
    Belderrain, TR
    Grubbs, RH
    ORGANOMETALLICS, 1999, 18 (07) : 1299 - 1304
12345