Catalytic oxidation of alkenes with ruthenium(II) perchlorate complexes

被引：10
|
作者：
Kanmani, AS [1 ]
Vancheesan, S [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 125卷 / 2-3期
关键词：
ruthenium(II) perchlorate; homogeneous; catalyst; cyclohexene; oxidation;
D O I：
10.1016/S1381-1169(97)00087-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ruthenium(II) perchlorate complexes, [Ru(dppm)(3)(ClO4)]ClO4, 1, Ru(dppe)(3)(ClO4)]ClO4, 2, [Ru(dpae)(3)(ClO4)]ClO4, 3, catalyse the oxidation of cyclohexene in the presence of cumene hydroperoxide (CHP) under homogeneous liquid phase. The products of oxidation are 2-cyclohexen-1-ol and 2-cyclohexenone. Linear alkenes like 1-heptene and 1-octene are not efficiently oxidised under these conditions. Solvent influences the rate of oxidation considerably. N-methylmorpholine-N-oxide (NMO) and CHP are compared for their oxidising ability. (C) 1997 Elsevier Science B.V.
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页码：127 / 134
页数：8
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