Catalytic oxidation of alkenes with ruthenium(II) perchlorate complexes

被引：10

作者：

Kanmani, AS ^{[1
]}

Vancheesan, S ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 125卷 / 2-3期

关键词：

ruthenium(II) perchlorate; homogeneous; catalyst; cyclohexene; oxidation;

D O I：

10.1016/S1381-1169(97)00087-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ruthenium(II) perchlorate complexes, [Ru(dppm)(3)(ClO4)]ClO4, 1, Ru(dppe)(3)(ClO4)]ClO4, 2, [Ru(dpae)(3)(ClO4)]ClO4, 3, catalyse the oxidation of cyclohexene in the presence of cumene hydroperoxide (CHP) under homogeneous liquid phase. The products of oxidation are 2-cyclohexen-1-ol and 2-cyclohexenone. Linear alkenes like 1-heptene and 1-octene are not efficiently oxidised under these conditions. Solvent influences the rate of oxidation considerably. N-methylmorpholine-N-oxide (NMO) and CHP are compared for their oxidising ability. (C) 1997 Elsevier Science B.V.

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页码：127 / 134

页数：8

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