Crystal structure of the adduct of lanthanum tris(hexafluoroacethylacetonate) with 1,10-phenanthroline La(Hfa)3(Phen)2

被引：0
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作者：
Rogachev, AY
Minacheva, LK
Sergienko, VS
Kuz'mina, NP
机构：
[1] Moscow State Pedag Univ, Moscow 119992, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 09期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of La(Hfa)(3)(Phen)(2) (Hfa = hexafluoroacetylacetonate ion) was determined by X-ray single-crystal diffraction. Crystals are monoclinic with a = 13.583(3) Angstrom, b = 16.959(3) Angstrom, c 18.860(4) Angstrom, 94.71(3)degrees, V = 4330(1) Angstrom(3), Z = 4, space group P2(1)/n, R = 0.052 for 2997 reflections with 1 > 2sigma(I). The lanthanum atom coordinates six oxygen atoms of three hexafluoroacetylacetonate ligands ((La-O)(av) = 2.548(4) Angstrom) and four nitrogen atoms of two phenanthroline molecules ((La-N)(av) = 2.773(8) Angstrom) in the vertices of a distorted sphenocorona.
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页码：1432 / 1439
页数：8
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