user

Crystal structure of the adduct of lanthanum tris(hexafluoroacethylacetonate) with 1,10-phenanthroline La(Hfa)3(Phen)2

被引：0
|
作者：
Rogachev, AY
Minacheva, LK
Sergienko, VS
Kuz'mina, NP
机构：
[1] Moscow State Pedag Univ, Moscow 119992, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of La(Hfa)(3)(Phen)(2) (Hfa = hexafluoroacetylacetonate ion) was determined by X-ray single-crystal diffraction. Crystals are monoclinic with a = 13.583(3) Angstrom, b = 16.959(3) Angstrom, c 18.860(4) Angstrom, 94.71(3)degrees, V = 4330(1) Angstrom(3), Z = 4, space group P2(1)/n, R = 0.052 for 2997 reflections with 1 > 2sigma(I). The lanthanum atom coordinates six oxygen atoms of three hexafluoroacetylacetonate ligands ((La-O)(av) = 2.548(4) Angstrom) and four nitrogen atoms of two phenanthroline molecules ((La-N)(av) = 2.773(8) Angstrom) in the vertices of a distorted sphenocorona.
引用
收藏
页码：1432 / 1439
页数：8
相关论文
共 50 条
  • [21] Crystal structures of [M(N-3)(2)(phen)(2)] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline
    Masarova, Petra
    Moncol, Jan
    ACTA CHIMICA SLOVACA, 2016, 9 (02): : 152 - 157
  • [22] Synthesis and the crystal and molecular structure of two modifications of bis(1,10-phenanthroline)trinitratoerbium(III) Er(NO3)3(Phen)2
    Sadikov, G. G.
    Antsyshkina, A. S.
    Kuznetsova, I. A.
    Rodnikova, M. N.
    CRYSTALLOGRAPHY REPORTS, 2006, 51 (02) : 271 - 277
  • [23] Synthesis and the crystal and molecular structure of two modifications of bis(1,10-phenanthroline)trinitratoerbium(III) Er(NO3)3(Phen)2
    G. G. Sadikov
    A. S. Antsyshkina
    I. A. Kuznetsova
    M. N. Rodnikova
    Crystallography Reports, 2006, 51 : 271 - 277
  • [24] CRYSTAL-STRUCTURE OF TRIS(2-METHYL-1,10-PHENANTHROLINE)IRON(II) TETRAPHENYLBORATE
    GOODWIN, HA
    KUCHARSKI, ES
    WHITE, AH
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (06) : 1115 - 1124
  • [25] Synthesis and structure of tris(dimethyldithiocarbamato) (1,10-phenanthroline)lanthanide complexes
    Kubat, Vaclav
    Demo, Gabriel
    Jeremias, Lukas
    Novosad, Josef
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2013, 228 (08): : 369 - 373
  • [26] Synthesis, crystal structure and thermal behaviour of Ba(hfa)2(Phen)2 and the crystal structure of Ba2(hfa)2(μ2-CF3COO)2(Phen)4 (hfa=hexafluoroacetylacetonate, Phen=o-Phenanthroline)
    Kuzmina, N
    Ryazanov, M
    Troyanov, S
    POLYHEDRON, 1999, 18 (16) : 2177 - 2184
  • [27] Crystal structure of adduct 2-phenyl-imidazo [4, 5-f]1,10-phenanthroline methanol
    Lin, HW
    Zhu, WX
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (08) : 1054 - 1058
  • [28] Crystal Structure of Adduct 2-Phenyl-imidazo[4,5-f] 1,10-phenanthroline Methanol
    林惠文
    朱文祥
    ChineseJournalofChemistry, 2003, (08) : 1054 - 1058
  • [29] Syntheses and crystal structures of Ln(phen)2(NO3)3 with Ln = Pr, Nd, Sm, Eu, Dy, and phen=1,10-phenanthroline
    Zheng, YQ
    Zhou, LX
    Lin, JL
    Zhang, SW
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (07): : 1643 - 1646
  • [30] Iron(II) tris(3-bromo-1,10-phenanthroline) complex: Synthesis, crystal structure and electropolymerization
    Lee, KJ
    Yoon, I
    Lee, SS
    Lee, BY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2002, 23 (03) : 399 - 403
12345