Synthetic studies on azadirachtin: Asymmetric synthesis of the tetracyclic decalin part of azadirachtin

被引：0
|
作者：
Kanoh, N [1 ]
Ishihara, J [1 ]
Yamamoto, Y [1 ]
Murai, A [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
来源：
SYNTHESIS-STUTTGART | 2000年 / 13期
关键词：
azadirachtin; insect antifeedant; decalin; CBS asymmetric reduction; intramolecular Diels-Alder reaction;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A synthesis of the tetracyclic decalin part of azadirachtin in the naturally occurring form is described. The key reactions involve the Corey-Bakshi-Shibata (CBS) asymmetric reduction of the ketone, and an intramolecular Diels-Alder (IMDA) reaction.
引用
收藏
页码：1878 / 1893
页数：16
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