Synthetic studies on azadirachtin: Asymmetric synthesis of the tetracyclic decalin part of azadirachtin

被引：0

作者：

Kanoh, N ^{[1
]}

Ishihara, J ^{[1
]}

Yamamoto, Y ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

SYNTHESIS-STUTTGART | 2000年 / 13期

关键词：

azadirachtin; insect antifeedant; decalin; CBS asymmetric reduction; intramolecular Diels-Alder reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthesis of the tetracyclic decalin part of azadirachtin in the naturally occurring form is described. The key reactions involve the Corey-Bakshi-Shibata (CBS) asymmetric reduction of the ketone, and an intramolecular Diels-Alder (IMDA) reaction.

引用

页码：1878 / 1893

页数：16

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