A model synthetic approach towards the furanacetal component of azadirachtin: a potent insect antifeedant

被引：7
|
作者：
Raina, S [1 ]
Prasad, BAB [1 ]
Singh, VK [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
ARKIVOC | 2003年
关键词：
alpha-D-glucose; azadirachtin; tandem radical cyclization;
D O I：
10.3998/ark.5550190.0004.303
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this article, a model synthetic approach towards the furanacetal component of azadirachtin has been described from alpha-D-glucose. Tandem radical cyclization was the key step for the formation of the desired tricyclic system. The reaction provided a bicyclic system instead of the desired tricyclic molecule. The reason for the unsuccessful tandem cyclization was proposed to be mainly energy factors.
引用
收藏
页码：16 / 24
页数：9
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