Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

被引：0
|
作者：
Sendil, Kivilcim [1 ]
Ozgun, H. Beytiye [2 ]
Ustun, Ebru [2 ]
机构：
[1] Kafkas Univ, Dept Chem, Fac Sci, TR-36100 Kars, Turkey
[2] Gazi Univ, Dept Chem, Fac Sci, TR-06100 Ankara, Turkey
来源：
JOURNAL OF CHEMISTRY | 2016年 / 2016卷
关键词：
PYRIDINIUM FLUOROCHROMATE; CARBONYL-COMPOUNDS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; OXIDANT; CHLOROCHROMATE; ALDEHYDES; MECHANISM; KINETICS; OXIMES;
D O I：
10.1155/2016/3518102
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation.
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页数：7
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