Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

被引：0

作者：

Sendil, Kivilcim ^{[1
]}

Ozgun, H. Beytiye ^{[2
]}

Ustun, Ebru ^{[2
]}

机构：

[1] Kafkas Univ, Dept Chem, Fac Sci, TR-36100 Kars, Turkey

[2] Gazi Univ, Dept Chem, Fac Sci, TR-06100 Ankara, Turkey

来源：

JOURNAL OF CHEMISTRY | 2016年 / 2016卷

关键词：

PYRIDINIUM FLUOROCHROMATE; CARBONYL-COMPOUNDS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; OXIDANT; CHLOROCHROMATE; ALDEHYDES; MECHANISM; KINETICS; OXIMES;

D O I：

10.1155/2016/3518102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation.

引用

页数：7

共 50 条

[21] Heteropolyacid catalyzed click synthesis of 5-substituted 1H-tetrazoles from [bmim]N3 and nitriles under solvent-free conditions
Fazeli, Azadeh
Oskooie, Hossein A.
Beheshtiha, Yahya S.
Heravi, Majid M.
Valizadeh, Hassan
Bamoharram, Fatemeh F.
MONATSHEFTE FUR CHEMIE, 2013, 144 (09): : 1407 - 1410
[22] Efficient Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones Catalyzed by a Cd-Based Covalent Organic Framework Under Solvent-Free Conditions
Nazifi, Maryam
Saeidian, Hamid
Taher, Salman
CHEMICAL METHODOLOGIES, 2024, 8 (07):
[23] An Efficient Synthesis of Multi-Substituted 3,4-Dihydropyrimidin-2(1H)-ones/thiones Under Solvent-Free Microwave Irradiation Using Alumina Sulfuric Acid
Shaterian, Hamid Reza
Hosseinian, Asghar
Ghashang, Majid
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (01) : 197 - 205
[24] Three component condensations catalyzed by iodine-alumina for the synthesis of substituted 3,4-dihydropyrimidin-2(1H)-ones under microwave irradiation and solvent-free conditions
Saxena, I
Borah, DC
Sarma, JC
TETRAHEDRON LETTERS, 2005, 46 (07) : 1159 - 1160
[25] New Efficient Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones Catalyzed by Benzotriazolium-Based Ionic Liquids under Solvent-Free Conditions
Liu, Zhiqing
Ma, Rong
Cao, Dawei
Liu, Chenjiang
MOLECULES, 2016, 21 (04):
[26] P2O5-SiO2 as an efficient heterogeneous catalyst for the solvent-free synthesis of 1-substituted 1H-1,2,3,4-tetrazoles under conventional and ultrasound irradiation conditions
Habibi, Davood
Nasrollahzadeh, Mahmoud
Mehrabi, Leila
Mostafaee, Samaneh
MONATSHEFTE FUR CHEMIE, 2013, 144 (05): : 725 - 728
[27] Ammonium Acetate Promoted Rapid and Efficient Synthesis of γ-Benzopyranones and 3,4-Dihydropyrimidin-2(1H)-ones/thiones Under Solvent-free Conditions: A Parallel Scrutiny of Microwave Irradiation versus Conventional Heating
Thorat, Nitin M.
Dengale, Rohit A.
Thopate, Shankar R.
Rohokale, Sandeep V.
LETTERS IN ORGANIC CHEMISTRY, 2015, 12 (08) : 574 - 583
[28] New hexaphosphane ligands 1,3,5-C6H3{p-C6H4N(PX2)2}3 [ X = Cl, F, C6H3OMe(C3H5)]: Synthesis, derivatization and palladium(II) and platinum(II) complexes
Rao, Sowmya
Ganesamoorthy, Chelladurai
Mobin, Shaikh M.
Balakrishna, Maravanji S.
DALTON TRANSACTIONS, 2011, 40 (22) : 5841 - 5843
[29] P2O5–SiO2 as an efficient heterogeneous catalyst for the solvent-free synthesis of 1-substituted 1H-1,2,3,4-tetrazoles under conventional and ultrasound irradiation conditions
Davood Habibi
Mahmoud Nasrollahzadeh
Leila Mehrabi
Samaneh Mostafaee
Monatshefte für Chemie - Chemical Monthly, 2013, 144 : 725 - 728
[30] NH3(CH2)5NH3BiCl5 as a new hybrid and efficient catalyst for the synthesis of 1-(benzothiazolylamino)methyl-2-naphthol derivatives under solvent-free conditions
Benzekri, Zakaria
Sibous, Sarra
Serrar, Houda
Ouasri, Ali
Boukhris, Said
Ghailane, Rachida
Rhandour, Ali
Souizi, Abdelaziz
Journal of Molecular Structure, 2021, 1202

← 1 2 3 4 5 →