Oxidative cleavage of unsaturated 1,2-diols using chiral lead-tetracarboxylates obtained by in situ metathesis

被引：0

作者：

Lena, JIC ^{[1
]}

Sesenoglu, Ö ^{[1
]}

Birlirakis, N ^{[1
]}

Arseniyadis, S ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 01期

关键词：

ring expansion; cascade transformations; acetate metathesis; chiral carboxylic solvents;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A combination of an acetate metathesis/cascade transformations process, providing ring enlarged systems decorated with a chiral auxiliary, is presented. The use of a chiral carboxylic acid, such as (S)-2-acetoxypropionic acid, gives diastereomeric mixtures when performed in the racemic series, offering the possibility of a chemical resolution. (C) 2000 Published by Elsevier Science Ltd.

引用

页码：21 / 24

页数：4

共 39 条

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