Oxidative cleavage of unsaturated 1,2-diols using chiral lead-tetracarboxylates obtained by in situ metathesis

被引：0
|
作者：
Lena, JIC [1 ]
Sesenoglu, Ö [1 ]
Birlirakis, N [1 ]
Arseniyadis, S [1 ]
机构：
[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 01期
关键词：
ring expansion; cascade transformations; acetate metathesis; chiral carboxylic solvents;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A combination of an acetate metathesis/cascade transformations process, providing ring enlarged systems decorated with a chiral auxiliary, is presented. The use of a chiral carboxylic acid, such as (S)-2-acetoxypropionic acid, gives diastereomeric mixtures when performed in the racemic series, offering the possibility of a chemical resolution. (C) 2000 Published by Elsevier Science Ltd.
引用
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页码：21 / 24
页数：4
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