Palladium-catalyzed Coupling of Benzoyl Halides with Aryltrifluorosilanes Leading to Diaryl Ketones

被引：46

作者：

Ogiwara, Yohei ^{[1
]}

Maegawa, Yuki ^{[1
]}

Sakino, Daisuke ^{[1
]}

Sakai, Norio ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Dept Pure & Appl Chem, Fac Sci & Technol, Noda, Chiba 2788510, Japan

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 07期

关键词：

Palladium catalyst; Acyl halide; Organosilicon compound; PREPARING AROMATIC KETONES; SUZUKI-MIYAURA TYPE; ACYL CHLORIDES; ACID-CHLORIDES; ARYLBORONIC ACIDS; GRIGNARD-REAGENTS; ORGANOTIN COMPOUNDS; CONVENIENT METHOD; ROOM-TEMPERATURE; SODIUM TETRAPHENYLBORATE;

D O I：

10.1246/cl.160223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acyl-aryl Hiyama coupling of acyl halides with arylsilanes has been achieved by employing a palladium/phosphine catalyst system. A variety of acyl chlorides and fluorides can be applied for coupling with arylsilicon reagents, and unsymmetrical benzophenone derivatives can be prepared using this protocol.

引用

页码：790 / 792

页数：3

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