Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides

被引：39
|
作者：
Molander, Gary A. [1 ]
Iannazzo, Laura [1 ]
机构：
[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 21期
关键词：
ORGANOSILICON COMPOUNDS; BOND FORMATION; BROMIDES; HALIDES; REAGENTS; ALKYLTRIFLUOROSILANES; ARYLSILOXANES; COMPLEX;
D O I：
10.1021/jo201840n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient, palladium-catalyzed Hiyama cross-coupling reaction of aryltrifluorosilanes with aryl chlorides has been developed. A wide variety of functionalized biaryl derivatives were isolated in good to excellent yields. The scope of this reaction has also been extended to heteroaryl chlorides, affording the corresponding heterobiaryl compounds in high yields.
引用
收藏
页码：9182 / 9187
页数：6
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