PALLADIUM-CATALYZED CROSS-COUPLING OF ARYL CHLORIDES WITH ARYLSILATRANES

被引：2
|
作者：
Yamamoto, Yutaro [1 ]
Baralle, Alexandre [1 ]
Godefroy, Anais [1 ]
Murakami, Kei [1 ]
Yorimitsu, Hideki [1 ]
Osuka, Atsuhiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
HETEROCYCLES | 2017年 / 95卷 / 01期
关键词：
ROOM-TEMPERATURE; REAGENTS; SILYLSILATRANES; NANOPARTICLES; SILATRANES; SILYLATION; ARYLATION; PROTOCOL; ATRANES; CARBON;
D O I：
10.3987/COM-16-S(S)21
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cross-coupling reactions of arylsilatranes with readily available and inexpensive aryl chlorides were carried out in toluene/THF at 100 degrees C for 3 h in the presence of tetrabutylammonium fluoride as an activator for smooth transmetalation and catalytic amounts of palladium(II) acetate and XPhos.
引用
收藏
页码：568 / 574
页数：7
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