Palladium-catalyzed Coupling of Benzoyl Halides with Aryltrifluorosilanes Leading to Diaryl Ketones

被引：46
|
作者：
Ogiwara, Yohei [1 ]
Maegawa, Yuki [1 ]
Sakino, Daisuke [1 ]
Sakai, Norio [1 ]
机构：
[1] Tokyo Univ Sci RIKADAI, Dept Pure & Appl Chem, Fac Sci & Technol, Noda, Chiba 2788510, Japan
来源：
CHEMISTRY LETTERS | 2016年 / 45卷 / 07期
关键词：
Palladium catalyst; Acyl halide; Organosilicon compound; PREPARING AROMATIC KETONES; SUZUKI-MIYAURA TYPE; ACYL CHLORIDES; ACID-CHLORIDES; ARYLBORONIC ACIDS; GRIGNARD-REAGENTS; ORGANOTIN COMPOUNDS; CONVENIENT METHOD; ROOM-TEMPERATURE; SODIUM TETRAPHENYLBORATE;
D O I：
10.1246/cl.160223
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acyl-aryl Hiyama coupling of acyl halides with arylsilanes has been achieved by employing a palladium/phosphine catalyst system. A variety of acyl chlorides and fluorides can be applied for coupling with arylsilicon reagents, and unsymmetrical benzophenone derivatives can be prepared using this protocol.
引用
收藏
页码：790 / 792
页数：3
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